Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond

Serena Fantasia; Heiko Jacobsen; Luigi Cavallo; Steven Patrick Nolan

doi:10.1021/om700447u

Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond

Serena Fantasia, Heiko Jacobsen, Luigi Cavallo, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.

Original language	English
Pages (from-to)	3286-3288
Number of pages	3
Journal	Organometallics
Volume	26
Issue number	14
DOIs	https://doi.org/10.1021/om700447u
Publication status	Published - 2 Jul 2007

Keywords

C-H ACTIVATION
OXIDATIVE ADDITION
ROOM-TEMPERATURE
SUZUKI-MIYAURA
TRANSESTERIFICATION/ACYLATION REACTIONS
PLATINUM(0)-CARBENE COMPLEXES
METATHESIS CATALYSTS
MIGRATORY INSERTION
BUCHWALD-HARTWIG
RUTHENIUM

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title = "Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond",

abstract = "The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.",

keywords = "C-H ACTIVATION, OXIDATIVE ADDITION, ROOM-TEMPERATURE, SUZUKI-MIYAURA, TRANSESTERIFICATION/ACYLATION REACTIONS, PLATINUM(0)-CARBENE COMPLEXES, METATHESIS CATALYSTS, MIGRATORY INSERTION, BUCHWALD-HARTWIG, RUTHENIUM",

author = "Serena Fantasia and Heiko Jacobsen and Luigi Cavallo and Nolan, {Steven Patrick}",

year = "2007",

month = jul,

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doi = "10.1021/om700447u",

language = "English",

volume = "26",

pages = "3286--3288",

journal = "Organometallics",

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publisher = "American Chemical Society (ACS)",

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T1 - Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond

AU - Fantasia, Serena

AU - Jacobsen, Heiko

AU - Cavallo, Luigi

AU - Nolan, Steven Patrick

PY - 2007/7/2

Y1 - 2007/7/2

N2 - The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.

AB - The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.

KW - C-H ACTIVATION

KW - OXIDATIVE ADDITION

KW - ROOM-TEMPERATURE

KW - SUZUKI-MIYAURA

KW - TRANSESTERIFICATION/ACYLATION REACTIONS

KW - PLATINUM(0)-CARBENE COMPLEXES

KW - METATHESIS CATALYSTS

KW - MIGRATORY INSERTION

KW - BUCHWALD-HARTWIG

KW - RUTHENIUM

UR - http://www.scopus.com/inward/record.url?scp=34547380848&partnerID=8YFLogxK

U2 - 10.1021/om700447u

DO - 10.1021/om700447u

M3 - Article

SN - 0276-7333

VL - 26

SP - 3286

EP - 3288

JO - Organometallics

JF - Organometallics

IS - 14

ER -

Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond

Abstract

Keywords

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