Inorganic and organometallic hemicage podates and cage cryptates incorporating a benzene platform

Eli Zysman-Colman*, Celine Denis

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

This review surveys the different binding motifs and properties of hemicaged and caged complexes bearing tripodal units with a benzene platform. Complexes of inorganic cations and anions are the objects of this review. The 1:1 stoichiometry frequently observed for hemicage host-guest complexes constitutes a general paradigm for binding, one to which is not always adhered. Insight into the impact of preorganization, host selectivity and functionality will become apparent. (C) 2012 Elsevier B.V. All rights reserved.

Original languageEnglish
Pages (from-to)1742-1761
Number of pages20
JournalCoordination Chemistry Reviews
Volume256
Issue number15-16
DOIs
Publication statusPublished - Aug 2012
Event19th International Symposium on the Photophysics and Photochemistry of Coordination Compounds (ISPPCC) - Strasbourg, France
Duration: 1 Jul 2011 → …

Keywords

  • Hemicages
  • Cages
  • Capsules
  • Metal complexes
  • Host-guest interactions
  • Molecular recognition
  • SUBSITE-DIFFERENTIATED ANALOGS
  • INDICATOR-DISPLACEMENT ASSAYS
  • CHIRAL MOLECULAR RECOGNITION
  • TRIPODAL ANION RECEPTOR
  • TEACHING OLD INDICATORS
  • DISK-SHAPED LIGANDS
  • PHOTOPHYSICAL PROPERTIES
  • SELECTIVE RECOGNITION
  • ARTIFICIAL RECEPTORS
  • SYNTHETIC RECEPTOR

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