N-Metallation of MS2N2 rings. X-ray crystal structures of [( η5-C5Me5)Ir(S2N2)Au(PPh3)][ClO4], [{( η5-C5Me5)Ir(S2N2)Au}2(μ2-dppm)][ClO4]2 and [Au(dppeS-P)Cl]2

SM Aucott; P Bhattacharyya; HL Milton; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1039/b306847a

N-Metallation of MS₂N₂ rings. X-ray crystal structures of [( η⁵-C₅Me₅)Ir(S₂N₂)Au(PPh₃)][ClO₄], [{( η⁵-C₅Me₅)Ir(S₂N₂)Au}₂(μ₂-dppm)][ClO₄]₂ and [Au(dppeS-P)Cl]₂

SM Aucott, P Bhattacharyya, HL Milton, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Bimetallic complexes [(eta(5)-C5R5)M(S2N2)Au(PPh3)][ClO4] and tetrametallic species [{(eta(5)-C5R5)M(S2N2)Au}(2)(mu(2)-(PP)-P-boolean AND)][ClO4](2) (R = H, M = Co; R = Me, M = Ir; (PP)-P-boolean AND = dppm or dppe) can be prepared by treatment of [(eta(5)-C5R5)M(S2N2)] with gold(I) electrophiles generated by chloride abstraction from [AuCl(PPh3)] or [(AuCl)(2)(mu(2)-(PP)-P-boolean AND)]. X-Ray crystallography of [(eta(5)-C5Me5) Ir(S2N2)Au(PPh3)][ClO4] and [{(eta(5)-C5Me5)Ir(S2N2)Au}(2)(mu(2)-dppm)][ClO4](2) confirms auration of the metal-bound nitrogen atom of the MS2N2 ring. pi-Stacking of the MS2N2 rings occurs within both structures.

Original language	English
Pages (from-to)	1466-1469
Number of pages	4
Journal	New Journal of Chemistry
Volume	27
Issue number	10
DOIs	https://doi.org/10.1039/b306847a
Publication status	Published - 2003

Keywords

SULFUR NITROGEN-COMPLEXES
SOLID-STATE STRUCTURES
BINUCLEAR COMPLEXES
STACKING COMPOUNDS
GOLD(I) CENTERS
LIGANDS
HETEROCYCLES
DERIVATIVES

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10.1039/b306847a

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@article{ea019a5a25424881baa1423bf7826d89,

title = "N-Metallation of MS2N2 rings. X-ray crystal structures of [( η5-C5Me5)Ir(S2N2)Au(PPh3)][ClO4], [\{( η5-C5Me5)Ir(S2N2)Au\}2(μ2-dppm)][ClO4]2 and [Au(dppeS-P)Cl]2",

abstract = "Bimetallic complexes [(eta(5)-C5R5)M(S2N2)Au(PPh3)][ClO4] and tetrametallic species [\{(eta(5)-C5R5)M(S2N2)Au\}(2)(mu(2)-(PP)-P-boolean AND)][ClO4](2) (R = H, M = Co; R = Me, M = Ir; (PP)-P-boolean AND = dppm or dppe) can be prepared by treatment of [(eta(5)-C5R5)M(S2N2)] with gold(I) electrophiles generated by chloride abstraction from [AuCl(PPh3)] or [(AuCl)(2)(mu(2)-(PP)-P-boolean AND)]. X-Ray crystallography of [(eta(5)-C5Me5) Ir(S2N2)Au(PPh3)][ClO4] and [\{(eta(5)-C5Me5)Ir(S2N2)Au\}(2)(mu(2)-dppm)][ClO4](2) confirms auration of the metal-bound nitrogen atom of the MS2N2 ring. pi-Stacking of the MS2N2 rings occurs within both structures.",

keywords = "SULFUR NITROGEN-COMPLEXES, SOLID-STATE STRUCTURES, BINUCLEAR COMPLEXES, STACKING COMPOUNDS, GOLD(I) CENTERS, LIGANDS, HETEROCYCLES, DERIVATIVES",

author = "SM Aucott and P Bhattacharyya and HL Milton and Slawin, \{Alexandra Martha Zoya\} and Woollins, \{John Derek\}",

year = "2003",

doi = "10.1039/b306847a",

language = "English",

volume = "27",

pages = "1466--1469",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - N-Metallation of MS2N2 rings. X-ray crystal structures of [( η5-C5Me5)Ir(S2N2)Au(PPh3)][ClO4], [{( η5-C5Me5)Ir(S2N2)Au}2(μ2-dppm)][ClO4]2 and [Au(dppeS-P)Cl]2

AU - Aucott, SM

AU - Bhattacharyya, P

AU - Milton, HL

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2003

Y1 - 2003

N2 - Bimetallic complexes [(eta(5)-C5R5)M(S2N2)Au(PPh3)][ClO4] and tetrametallic species [{(eta(5)-C5R5)M(S2N2)Au}(2)(mu(2)-(PP)-P-boolean AND)][ClO4](2) (R = H, M = Co; R = Me, M = Ir; (PP)-P-boolean AND = dppm or dppe) can be prepared by treatment of [(eta(5)-C5R5)M(S2N2)] with gold(I) electrophiles generated by chloride abstraction from [AuCl(PPh3)] or [(AuCl)(2)(mu(2)-(PP)-P-boolean AND)]. X-Ray crystallography of [(eta(5)-C5Me5) Ir(S2N2)Au(PPh3)][ClO4] and [{(eta(5)-C5Me5)Ir(S2N2)Au}(2)(mu(2)-dppm)][ClO4](2) confirms auration of the metal-bound nitrogen atom of the MS2N2 ring. pi-Stacking of the MS2N2 rings occurs within both structures.

AB - Bimetallic complexes [(eta(5)-C5R5)M(S2N2)Au(PPh3)][ClO4] and tetrametallic species [{(eta(5)-C5R5)M(S2N2)Au}(2)(mu(2)-(PP)-P-boolean AND)][ClO4](2) (R = H, M = Co; R = Me, M = Ir; (PP)-P-boolean AND = dppm or dppe) can be prepared by treatment of [(eta(5)-C5R5)M(S2N2)] with gold(I) electrophiles generated by chloride abstraction from [AuCl(PPh3)] or [(AuCl)(2)(mu(2)-(PP)-P-boolean AND)]. X-Ray crystallography of [(eta(5)-C5Me5) Ir(S2N2)Au(PPh3)][ClO4] and [{(eta(5)-C5Me5)Ir(S2N2)Au}(2)(mu(2)-dppm)][ClO4](2) confirms auration of the metal-bound nitrogen atom of the MS2N2 ring. pi-Stacking of the MS2N2 rings occurs within both structures.

KW - SULFUR NITROGEN-COMPLEXES

KW - SOLID-STATE STRUCTURES

KW - BINUCLEAR COMPLEXES

KW - STACKING COMPOUNDS

KW - GOLD(I) CENTERS

KW - LIGANDS

KW - HETEROCYCLES

KW - DERIVATIVES

UR - https://www.scopus.com/pages/publications/0142218012

U2 - 10.1039/b306847a

DO - 10.1039/b306847a

M3 - Article

SN - 1144-0546

VL - 27

SP - 1466

EP - 1469

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 10

ER -

N-Metallation of MS₂N₂ rings. X-ray crystal structures of [( η⁵-C₅Me₅)Ir(S₂N₂)Au(PPh₃)][ClO₄], [{( η⁵-C₅Me₅)Ir(S₂N₂)Au}₂(μ₂-dppm)][ClO₄]₂ and [Au(dppeS-P)Cl]₂

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