Indenylidene-imidazolylidene complexes of ruthenium as ring-closing metathesis catalysts

L  Jafarpour; H J  Schanz; E D  Stevens; Steven Patrick Nolan

doi:10.1021/om990587u

Indenylidene-imidazolylidene complexes of ruthenium as ring-closing metathesis catalysts

L Jafarpour, H J Schanz, E D Stevens, Steven Patrick Nolan

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Abstract

The indenylidene-imidazolylidene complexes of ruthenium (IMes)(PR3)Cl2Ru(3-phenylindenylid-1-ene) and (IPr)(PR3)Cl2Ru(3-phenylindenylid-1-ene) (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, IPr = 1,3-bis(2, 6-diisopropylphenyl)imidazol-2-ylidene and R = Ph, Cy) were prepared and found to be efficient catalyst precursors for ring-closing metathesis.

Original language	English
Pages (from-to)	5416-5419
Number of pages	4
Journal	Organometallics
Volume	18
Issue number	25
DOIs	https://doi.org/10.1021/om990587u
Publication status	Published - 6 Dec 1999

Keywords

OLEFIN METATHESIS
ORGANIC-SYNTHESIS
RUCL2(=CHR')(PR(3))(2)
CARBENE

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title = "Indenylidene-imidazolylidene complexes of ruthenium as ring-closing metathesis catalysts",

abstract = "The indenylidene-imidazolylidene complexes of ruthenium (IMes)(PR3)Cl2Ru(3-phenylindenylid-1-ene) and (IPr)(PR3)Cl2Ru(3-phenylindenylid-1-ene) (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, IPr = 1,3-bis(2, 6-diisopropylphenyl)imidazol-2-ylidene and R = Ph, Cy) were prepared and found to be efficient catalyst precursors for ring-closing metathesis.",

keywords = "OLEFIN METATHESIS, ORGANIC-SYNTHESIS, RUCL2(=CHR')(PR(3))(2), CARBENE",

author = "L Jafarpour and Schanz, \{H J\} and Stevens, \{E D\} and Nolan, \{Steven Patrick\}",

year = "1999",

month = dec,

day = "6",

doi = "10.1021/om990587u",

language = "English",

volume = "18",

pages = "5416--5419",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society (ACS)",

number = "25",

}

TY - JOUR

T1 - Indenylidene-imidazolylidene complexes of ruthenium as ring-closing metathesis catalysts

AU - Jafarpour, L

AU - Schanz, H J

AU - Stevens, E D

AU - Nolan, Steven Patrick

PY - 1999/12/6

Y1 - 1999/12/6

N2 - The indenylidene-imidazolylidene complexes of ruthenium (IMes)(PR3)Cl2Ru(3-phenylindenylid-1-ene) and (IPr)(PR3)Cl2Ru(3-phenylindenylid-1-ene) (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, IPr = 1,3-bis(2, 6-diisopropylphenyl)imidazol-2-ylidene and R = Ph, Cy) were prepared and found to be efficient catalyst precursors for ring-closing metathesis.

AB - The indenylidene-imidazolylidene complexes of ruthenium (IMes)(PR3)Cl2Ru(3-phenylindenylid-1-ene) and (IPr)(PR3)Cl2Ru(3-phenylindenylid-1-ene) (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, IPr = 1,3-bis(2, 6-diisopropylphenyl)imidazol-2-ylidene and R = Ph, Cy) were prepared and found to be efficient catalyst precursors for ring-closing metathesis.

KW - OLEFIN METATHESIS

KW - ORGANIC-SYNTHESIS

KW - RUCL2(=CHR')(PR(3))(2)

KW - CARBENE

UR - https://www.scopus.com/pages/publications/0000713963

U2 - 10.1021/om990587u

DO - 10.1021/om990587u

M3 - Article

SN - 0276-7333

VL - 18

SP - 5416

EP - 5419

JO - Organometallics

JF - Organometallics

IS - 25

ER -

Indenylidene-imidazolylidene complexes of ruthenium as ring-closing metathesis catalysts

Abstract

Keywords

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