Increasing the dimensionality of hybrid vanadium oxyfluorides using ionothermal synthesis

Farida Himeur Himeur; Phoebe Allan; Simon J. Teat; Richard John Goff; Russell Edward Morris; Philip Lightfoot

doi:10.1039/c000318b

Increasing the dimensionality of hybrid vanadium oxyfluorides using ionothermal synthesis

Farida Himeur Himeur, Phoebe Allan, Simon J. Teat, Richard John Goff, Russell Edward Morris, Philip Lightfoot

Research output: Contribution to journal › Article › peer-review

Abstract

A unique organically-templated vanadium(IV) oxyfluoride, [pyH][V2O2F5] has been prepared using an ionothermal approach. This compound has a novel layered structure which may be considered as arising via condensation of previously known 'ladder-like' structural building units. This suggests that ionothermal synthesis may provide a more effective route to extended network structures in these systems than the more widely explored hydrothermal-based media.

Original language	English
Pages (from-to)	6018-6020
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	26
Early online date	8 Mar 2010
DOIs	https://doi.org/10.1039/c000318b
Publication status	Published - 14 Jul 2010

Keywords

(VO)(2)P2O7
TEMPLATE

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10.1039/c000318b

Cite this

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abstract = "A unique organically-templated vanadium(IV) oxyfluoride, [pyH][V2O2F5] has been prepared using an ionothermal approach. This compound has a novel layered structure which may be considered as arising via condensation of previously known 'ladder-like' structural building units. This suggests that ionothermal synthesis may provide a more effective route to extended network structures in these systems than the more widely explored hydrothermal-based media.",

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doi = "10.1039/c000318b",

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publisher = "Royal Society of Chemistry",

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AU - Himeur, Farida Himeur

AU - Allan, Phoebe

AU - Teat, Simon J.

AU - Goff, Richard John

AU - Morris, Russell Edward

AU - Lightfoot, Philip

PY - 2010/7/14

Y1 - 2010/7/14

N2 - A unique organically-templated vanadium(IV) oxyfluoride, [pyH][V2O2F5] has been prepared using an ionothermal approach. This compound has a novel layered structure which may be considered as arising via condensation of previously known 'ladder-like' structural building units. This suggests that ionothermal synthesis may provide a more effective route to extended network structures in these systems than the more widely explored hydrothermal-based media.

AB - A unique organically-templated vanadium(IV) oxyfluoride, [pyH][V2O2F5] has been prepared using an ionothermal approach. This compound has a novel layered structure which may be considered as arising via condensation of previously known 'ladder-like' structural building units. This suggests that ionothermal synthesis may provide a more effective route to extended network structures in these systems than the more widely explored hydrothermal-based media.

KW - (VO)(2)P2O7

KW - TEMPLATE

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U2 - 10.1039/c000318b

DO - 10.1039/c000318b

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EP - 6020

JO - Dalton Transactions

JF - Dalton Transactions

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ER -

Increasing the dimensionality of hybrid vanadium oxyfluorides using ionothermal synthesis

Abstract

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Extending Ionothermal Synthesis: Extending Ionothermal Synthesis

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Increasing the dimensionality of hybrid vanadium oxyfluorides using ionothermal synthesis

Abstract

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Extending Ionothermal Synthesis: Extending Ionothermal Synthesis

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