Increasing the dimensionality of hybrid vanadium oxyfluorides using ionothermal synthesis

Farida Himeur Himeur, Phoebe Allan, Simon J. Teat, Richard John Goff, Russell Edward Morris, Philip Lightfoot

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

A unique organically-templated vanadium(IV) oxyfluoride, [pyH][V2O2F5] has been prepared using an ionothermal approach. This compound has a novel layered structure which may be considered as arising via condensation of previously known 'ladder-like' structural building units. This suggests that ionothermal synthesis may provide a more effective route to extended network structures in these systems than the more widely explored hydrothermal-based media.

Original languageEnglish
Pages (from-to)6018-6020
Number of pages3
JournalDalton Transactions
Volume39
Issue number26
Early online date8 Mar 2010
DOIs
Publication statusPublished - 14 Jul 2010

Keywords

  • (VO)(2)P2O7
  • TEMPLATE

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