Increased selectivity in hydroformylation reactions using dendrimer based catalysts; a positive dendrimer effect

Loic Melard Ropartz, Russell Edward Morris, D F Foster, David John Cole-Hamilton

Research output: Contribution to journalArticlepeer-review

128 Citations (Scopus)

Abstract

Dendrimers based on polyhedral oligomeric silsesquioxanes (POSS) cores with 16 PPh2 arms give much higher linear selectivities (14:1) than their small molecule analogues (3-4:1) in the hydroformylation of oct-1-ene.

Original languageEnglish
Pages (from-to)361-362
Number of pages2
JournalChemical Communications
Issue number4
DOIs
Publication statusPublished - 2001

Keywords

  • CARBOSILANE DENDRIMERS
  • MEMBRANE REACTOR
  • REGIOSELECTIVITY
  • LIGANDS

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