Increased selectivity in hydroformylation reactions using dendrimer based catalysts; a positive dendrimer effect

Loic Melard Ropartz; Russell Edward Morris; D F  Foster; David John Cole-Hamilton

doi:10.1039/B009574P

Increased selectivity in hydroformylation reactions using dendrimer based catalysts; a positive dendrimer effect

Loic Melard Ropartz, Russell Edward Morris, D F Foster, David John Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

Dendrimers based on polyhedral oligomeric silsesquioxanes (POSS) cores with 16 PPh2 arms give much higher linear selectivities (14:1) than their small molecule analogues (3-4:1) in the hydroformylation of oct-1-ene.

Original language	English
Pages (from-to)	361-362
Number of pages	2
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/B009574P
Publication status	Published - 2001

Keywords

CARBOSILANE DENDRIMERS
MEMBRANE REACTOR
REGIOSELECTIVITY
LIGANDS

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10.1039/B009574P

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title = "Increased selectivity in hydroformylation reactions using dendrimer based catalysts; a positive dendrimer effect",

abstract = "Dendrimers based on polyhedral oligomeric silsesquioxanes (POSS) cores with 16 PPh2 arms give much higher linear selectivities (14:1) than their small molecule analogues (3-4:1) in the hydroformylation of oct-1-ene.",

keywords = "CARBOSILANE DENDRIMERS, MEMBRANE REACTOR, REGIOSELECTIVITY, LIGANDS",

author = "Ropartz, {Loic Melard} and Morris, {Russell Edward} and Foster, {D F} and Cole-Hamilton, {David John}",

year = "2001",

doi = "10.1039/B009574P",

language = "English",

pages = "361--362",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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AU - Ropartz, Loic Melard

AU - Morris, Russell Edward

AU - Foster, D F

AU - Cole-Hamilton, David John

PY - 2001

Y1 - 2001

N2 - Dendrimers based on polyhedral oligomeric silsesquioxanes (POSS) cores with 16 PPh2 arms give much higher linear selectivities (14:1) than their small molecule analogues (3-4:1) in the hydroformylation of oct-1-ene.

AB - Dendrimers based on polyhedral oligomeric silsesquioxanes (POSS) cores with 16 PPh2 arms give much higher linear selectivities (14:1) than their small molecule analogues (3-4:1) in the hydroformylation of oct-1-ene.

KW - CARBOSILANE DENDRIMERS

KW - MEMBRANE REACTOR

KW - REGIOSELECTIVITY

KW - LIGANDS

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U2 - 10.1039/B009574P

DO - 10.1039/B009574P

M3 - Article

SN - 1359-7345

SP - 361

EP - 362

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

Increased selectivity in hydroformylation reactions using dendrimer based catalysts; a positive dendrimer effect

Abstract

Keywords

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