Incommensurate-commensurate transition in the geometric ferroelectric LaTaO4

Grant William Howieson, Shitao Wu, Alexandra S Gibbs, Wuzong Zhou, James Floyd Scott, Finlay D. Morrison

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)
6 Downloads (Pure)

Abstract

The layered perovskite LaTaO4 has been synthesized to be stable in both (polar) orthorhombic and (nonpolar) monoclinic polymorphs at ambient conditions. Although the structural transition between monoclinic and orthorhombic phases has been well established, there is some controversy regarding a further, unidentified transition around 500 K. Here this is identified as an incommensurate–commensurate first‐order transition between incommensurate Cmc21(α00)0s0 and commensurate Cmc21 orthorhombic phases. Transmission electron microscopy indicates partially ordered stacking of different structural units in a, identifying the local cause for the modulation, whereas variable temperature powder neutron diffraction has shown the overall macroscopic modulation vector, q ≈ (0.456, 0, 0)—roughly a 2.2 × expansion in a, corresponding to an approximate 11a commensurate superunit cell dimension. The modulation shows a continuous temperature dependence until transitioning to the basic (commensurate) cell at TIC‐C. Doping the interlayer La sites with smaller Nd cations stabilizes the incommensuration to higher temperature, suggesting the modulation is geometrically driven at the A site.
Original languageEnglish
Article number2004667
Number of pages10
JournalAdvanced Functional Materials
Volume30
Issue number45
Early online date6 Sept 2020
DOIs
Publication statusPublished - 4 Nov 2020

Keywords

  • Dielectrics
  • Ferroics
  • Structure-property relationships

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