Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks

Pascal G. Yot; Ke Yang; Vincent Guillerm; Florence Ragon; Vladimir Dmitriev; Paraskevas Parisiades; Erik Elkaïm; Thomas Devic; Patricia Horcajada; Christian Serre; Norbert Stock; John P. S. Mowat; Paul A. Wright; Gérard Férey; Guillaume Maurin

doi:10.1002/ejic.201600263

Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks

Pascal G. Yot, Ke Yang, Vincent Guillerm, Florence Ragon, Vladimir Dmitriev, Paraskevas Parisiades, Erik Elkaïm, Thomas Devic, Patricia Horcajada, Christian Serre, Norbert Stock, John P. S. Mowat, Paul A. Wright, Gérard Férey, Guillaume Maurin

Research output: Contribution to journal › Article › peer-review

Abstract

An extended series of MIL-53(M)_X metal–organic frameworks (MIL = Materials of Institute Lavoisier; M = Al, Cr, Fe, Sc; X = Cl, CH₃, NO₂) have been systematically investiaged to explore the impact of the nature of both the metal centre and the functions grafted on to the organic linker on the mechanical behaviour of this family of highly flexible hybrid porous frameworks under the application of an external pressure of up to 3 GPa. The high-pressure X-ray diffraction measurements allowed the characterization of the pressure-induced phase transitions of the hydrated structures, the associated volume changes/pressure transitions, and their mechanical resilience through the determination of their bulk moduli.

Original language	English
Pages (from-to)	4424–4429
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Volume	2016
Issue number	27
Early online date	4 Jul 2016
DOIs	https://doi.org/10.1002/ejic.201600263
Publication status	Published - 27 Sept 2016

Keywords

Metal–organic frameworks
Mechanical properties
X-ray diffraction
Phase transitions
Substituent effects

Access to Document

10.1002/ejic.201600263

Wright_2016_EJIC_MIL-53Metal-Organic_AAM
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/ejic.201600263
Accepted author manuscript, 1.1 MB
SuppInfo_Wright_2016_EJIC
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/ejic.201600263
Accepted author manuscript, 830 KB

Cite this

Yot, P. G., Yang, K., Guillerm, V., Ragon, F., Dmitriev, V., Parisiades, P., Elkaïm, E., Devic, T., Horcajada, P., Serre, C., Stock, N., Mowat, J. P. S., Wright, P. A., Férey, G., & Maurin, G. (2016). Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks. European Journal of Inorganic Chemistry, 2016(27), 4424–4429. https://doi.org/10.1002/ejic.201600263

@article{4004c2efbc484a2481c48ac74cd12263,

title = "Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks",

abstract = "An extended series of MIL-53(M)_X metal–organic frameworks (MIL = Materials of Institute Lavoisier; M = Al, Cr, Fe, Sc; X = Cl, CH3, NO2) have been systematically investiaged to explore the impact of the nature of both the metal centre and the functions grafted on to the organic linker on the mechanical behaviour of this family of highly flexible hybrid porous frameworks under the application of an external pressure of up to 3 GPa. The high-pressure X-ray diffraction measurements allowed the characterization of the pressure-induced phase transitions of the hydrated structures, the associated volume changes/pressure transitions, and their mechanical resilience through the determination of their bulk moduli.",

keywords = "Metal–organic frameworks, Mechanical properties, X-ray diffraction, Phase transitions, Substituent effects",

author = "Yot, {Pascal G.} and Ke Yang and Vincent Guillerm and Florence Ragon and Vladimir Dmitriev and Paraskevas Parisiades and Erik Elka{\"i}m and Thomas Devic and Patricia Horcajada and Christian Serre and Norbert Stock and Mowat, {John P. S.} and Wright, {Paul A.} and G{\'e}rard F{\'e}rey and Guillaume Maurin",

note = "The French National Agency for Research ANR “MODS” (ANR-12-BS10-0005) is thanked for its financial support. ",

year = "2016",

month = sep,

day = "27",

doi = "10.1002/ejic.201600263",

language = "English",

volume = "2016",

pages = "4424–4429",

journal = "European Journal of Inorganic Chemistry",

issn = "1099-0682",

publisher = "Wiley-Blackwell",

number = "27",

}

Yot, PG, Yang, K, Guillerm, V, Ragon, F, Dmitriev, V, Parisiades, P, Elkaïm, E, Devic, T, Horcajada, P, Serre, C, Stock, N, Mowat, JPS, Wright, PA, Férey, G & Maurin, G 2016, 'Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks', European Journal of Inorganic Chemistry, vol. 2016, no. 27, pp. 4424–4429. https://doi.org/10.1002/ejic.201600263

TY - JOUR

T1 - Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks

AU - Yot, Pascal G.

AU - Yang, Ke

AU - Guillerm, Vincent

AU - Ragon, Florence

AU - Dmitriev, Vladimir

AU - Parisiades, Paraskevas

AU - Elkaïm, Erik

AU - Devic, Thomas

AU - Horcajada, Patricia

AU - Serre, Christian

AU - Stock, Norbert

AU - Mowat, John P. S.

AU - Wright, Paul A.

AU - Férey, Gérard

AU - Maurin, Guillaume

N1 - The French National Agency for Research ANR “MODS” (ANR-12-BS10-0005) is thanked for its financial support.

PY - 2016/9/27

Y1 - 2016/9/27

N2 - An extended series of MIL-53(M)_X metal–organic frameworks (MIL = Materials of Institute Lavoisier; M = Al, Cr, Fe, Sc; X = Cl, CH3, NO2) have been systematically investiaged to explore the impact of the nature of both the metal centre and the functions grafted on to the organic linker on the mechanical behaviour of this family of highly flexible hybrid porous frameworks under the application of an external pressure of up to 3 GPa. The high-pressure X-ray diffraction measurements allowed the characterization of the pressure-induced phase transitions of the hydrated structures, the associated volume changes/pressure transitions, and their mechanical resilience through the determination of their bulk moduli.

AB - An extended series of MIL-53(M)_X metal–organic frameworks (MIL = Materials of Institute Lavoisier; M = Al, Cr, Fe, Sc; X = Cl, CH3, NO2) have been systematically investiaged to explore the impact of the nature of both the metal centre and the functions grafted on to the organic linker on the mechanical behaviour of this family of highly flexible hybrid porous frameworks under the application of an external pressure of up to 3 GPa. The high-pressure X-ray diffraction measurements allowed the characterization of the pressure-induced phase transitions of the hydrated structures, the associated volume changes/pressure transitions, and their mechanical resilience through the determination of their bulk moduli.

KW - Metal–organic frameworks

KW - Mechanical properties

KW - X-ray diffraction

KW - Phase transitions

KW - Substituent effects

UR - http://onlinelibrary.wiley.com/doi/10.1002/ejic.201600263/abstract#footer-support-info

U2 - 10.1002/ejic.201600263

DO - 10.1002/ejic.201600263

M3 - Article

SN - 1099-0682

VL - 2016

SP - 4424

EP - 4429

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 27

ER -

Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this