In-situ thermal battery discharge using NiS2 as a cathode material

Julia L. Payne; Julia D. Percival; Kyriakos Giagloglou; Christina J. Crouch; George M. Carins; Ronald I. Smith; Robert Comrie; Robert K. B. Gover; John T. S. Irvine

doi:10.1002/celc.201700095

In-situ thermal battery discharge using NiS₂ as a cathode material

Julia L. Payne^*, Julia D. Percival, Kyriakos Giagloglou, Christina J. Crouch, George M. Carins, Ronald I. Smith, Robert Comrie, Robert K. B. Gover, John T. S. Irvine^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

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Abstract

NiS₂ is a cathode material found in primary batteries which operate at high temperature. Herein we report the in situ battery discharge study of a thermal battery cell which uses NiS₂ as a cathode, using simultaneous collection of powder neutron diffraction data and electrochemical data. Five different regions were observed upon battery discharge and the evolution of nickel sulfide phases has been studied. Four different nickel-containing phases are observed during discharge (NiS₂, NiS, Ni₃S₂ and Ni). A new discharge mechanism has been proposed which does not include Ni₇S₆. Multiphase quantitative Rietveld refinement has allowed the percentages of the phases to be monitored during discharge. High intensity synchrotron powder X-ray diffraction has been used to study the resulting phases present in the cathode after battery discharge.

Original language	English
Pages (from-to)	1916-1923
Number of pages	8
Journal	ChemElectroChem
Volume	4
Issue number	8
Early online date	27 Apr 2017
DOIs	https://doi.org/10.1002/celc.201700095
Publication status	Published - 14 Aug 2017

Keywords

Cathodes
Electrochemistry
Nickel disulfide
Neutron diffraction
Thermal batteries

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Payne_2017_CEC_ThermalBatteryDischarge_CC
© 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Final published version, 2.92 MBLicence: CC BY

Energy Materials Discovery: Energy Materials Discovery Characterisation and Application
Irvine, J. T. S. (PI), Cassidy, M. (CoI), Connor, P. A. (CoI), Savaniu, C. D. (CoI) & Zhou, W. (CoI)
EPSRC
7/01/13 → 6/01/18
Project: Standard
Royal Society Wolfson Merit Award: Closing the Carbon Cycle with Solid State Electrochemistry
Irvine, J. T. S. (PI)
The Royal Society
1/08/12 → 31/07/17
Project: Standard

Julia Louise Payne
- jlp8st-andrews.acuk
- School of Chemistry - Lecturer in Inorganic Chemistry
- Institute of Behavioural and Neural Sciences
Person: Academic, Academic - Research

Data underpinning - In-Situ Thermal Battery Discharge using NiS2 as a Cathode Material
Payne, J. L. (Creator), Percival, J. (Creator), Giagloglou, K. (Creator), Crouch, C. (Creator), Carins, G. M. (Creator), Smith, R. (Creator), Comrie, R. (Creator), Gover, R. (Creator) & Irvine, J. T. S. (Creator), University of St Andrews, 3 May 2017
DOI: 10.17630/92155136-9404-4844-a958-5de1e1af2c66
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File

Cite this

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abstract = "NiS2 is a cathode material found in primary batteries which operate at high temperature. Herein we report the in situ battery discharge study of a thermal battery cell which uses NiS2 as a cathode, using simultaneous collection of powder neutron diffraction data and electrochemical data. Five different regions were observed upon battery discharge and the evolution of nickel sulfide phases has been studied. Four different nickel-containing phases are observed during discharge (NiS2, NiS, Ni3S2 and Ni). A new discharge mechanism has been proposed which does not include Ni7S6. Multiphase quantitative Rietveld refinement has allowed the percentages of the phases to be monitored during discharge. High intensity synchrotron powder X-ray diffraction has been used to study the resulting phases present in the cathode after battery discharge.",

keywords = "Cathodes, Electrochemistry, Nickel disulfide, Neutron diffraction, Thermal batteries",

author = "Payne, {Julia L.} and Percival, {Julia D.} and Kyriakos Giagloglou and Crouch, {Christina J.} and Carins, {George M.} and Smith, {Ronald I.} and Robert Comrie and Gover, {Robert K. B.} and Irvine, {John T. S.}",

note = "We thank AWE and the EPSRC (EP/K015540/1) for funding. JTSI acknowledges a Royal Society Wolfson Research Merit award. The research data supporting this publication can be accessed at https://doi.org/10.17630/92155136-9404-4844-a958-5de1e1af2c66",

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month = aug,

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doi = "10.1002/celc.201700095",

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AU - Payne, Julia L.

AU - Percival, Julia D.

AU - Giagloglou, Kyriakos

AU - Crouch, Christina J.

AU - Carins, George M.

AU - Smith, Ronald I.

AU - Comrie, Robert

AU - Gover, Robert K. B.

AU - Irvine, John T. S.

N1 - We thank AWE and the EPSRC (EP/K015540/1) for funding. JTSI acknowledges a Royal Society Wolfson Research Merit award. The research data supporting this publication can be accessed at https://doi.org/10.17630/92155136-9404-4844-a958-5de1e1af2c66

PY - 2017/8/14

Y1 - 2017/8/14

N2 - NiS2 is a cathode material found in primary batteries which operate at high temperature. Herein we report the in situ battery discharge study of a thermal battery cell which uses NiS2 as a cathode, using simultaneous collection of powder neutron diffraction data and electrochemical data. Five different regions were observed upon battery discharge and the evolution of nickel sulfide phases has been studied. Four different nickel-containing phases are observed during discharge (NiS2, NiS, Ni3S2 and Ni). A new discharge mechanism has been proposed which does not include Ni7S6. Multiphase quantitative Rietveld refinement has allowed the percentages of the phases to be monitored during discharge. High intensity synchrotron powder X-ray diffraction has been used to study the resulting phases present in the cathode after battery discharge.

AB - NiS2 is a cathode material found in primary batteries which operate at high temperature. Herein we report the in situ battery discharge study of a thermal battery cell which uses NiS2 as a cathode, using simultaneous collection of powder neutron diffraction data and electrochemical data. Five different regions were observed upon battery discharge and the evolution of nickel sulfide phases has been studied. Four different nickel-containing phases are observed during discharge (NiS2, NiS, Ni3S2 and Ni). A new discharge mechanism has been proposed which does not include Ni7S6. Multiphase quantitative Rietveld refinement has allowed the percentages of the phases to be monitored during discharge. High intensity synchrotron powder X-ray diffraction has been used to study the resulting phases present in the cathode after battery discharge.

KW - Cathodes

KW - Electrochemistry

KW - Nickel disulfide

KW - Neutron diffraction

KW - Thermal batteries

U2 - 10.1002/celc.201700095

DO - 10.1002/celc.201700095

M3 - Article

SN - 2196-0216

VL - 4

SP - 1916

EP - 1923

JO - ChemElectroChem

JF - ChemElectroChem

IS - 8

ER -

In-situ thermal battery discharge using NiS2 as a cathode material

Abstract

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Projects

Energy Materials Discovery: Energy Materials Discovery Characterisation and Application

Royal Society Wolfson Merit Award: Closing the Carbon Cycle with Solid State Electrochemistry

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Julia Louise Payne

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Data underpinning - In-Situ Thermal Battery Discharge using NiS2 as a Cathode Material

Cite this

In-situ thermal battery discharge using NiS₂ as a cathode material