In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

Joe C. Goodall; M. Arif Sajjad; Emily A. Thompson; Samuel J. Page; Adam M. Kerrigan; Huw T. Jenkins; Jason M. Lynam; Stuart A. Macgregor; Andrew S. Weller

doi:10.1039/d3cc03201a

In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

Joe C. Goodall, M. Arif Sajjad, Emily A. Thompson, Samuel J. Page, Adam M. Kerrigan, Huw T. Jenkins^*, Jason M. Lynam^*, Stuart A. Macgregor^*, Andrew S. Weller^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The group 7 complexes [M(κ³-2,6-(R₂PO)₂C₅H₃N)(CO)₂L][BAr^F₄] [M = Mn, R = ⁱPr, L = THF; M = Re, R = ^tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BAr^F₄] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.

Original language	English
Pages (from-to)	10749-10752
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	72
Early online date	7 Aug 2023
DOIs	https://doi.org/10.1039/d3cc03201a
Publication status	Published - 16 Sept 2023

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© 2023 The Author(s). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/). You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.
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CCDC 2271683 - 2271688 & 2271690: Experimental Crystal Structure Determination
Goodall, J. C. (Creator), Sajjad, M. A. (Creator), Thompson, E. A. (Creator), Page, S. J. (Creator), Kerrigan, A. M. (Creator), Jenkins, H. T. (Creator), Lynam, J. M. (Creator), Macgregor, S. A. (Creator) & Weller, A. S. (Creator), Cambridge Crystallographic Data Centre, 2023
DOI: 10.5517/ccdc.csd.cc2g7w3q, https://dx.doi.org/10.5517/ccdc.csd.cc2g7w4r and 5 more links, https://dx.doi.org/10.5517/ccdc.csd.cc2g7w5s, https://dx.doi.org/10.5517/ccdc.csd.cc2g7w6t, https://dx.doi.org/10.5517/ccdc.csd.cc2g7w7v, https://dx.doi.org/10.5517/ccdc.csd.cc2g7w8w, https://dx.doi.org/10.5517/ccdc.csd.cc2g7wby (show fewer)
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@article{84144d641c724b8ba69cdec38ce612ea,

title = "In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes",

abstract = "The group 7 complexes [M(κ3-2,6-(R2PO)2C5H3N)(CO)2L][BArF4] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BArF4] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity. ",

author = "Goodall, {Joe C.} and Sajjad, {M. Arif} and Thompson, {Emily A.} and Page, {Samuel J.} and Kerrigan, {Adam M.} and Jenkins, {Huw T.} and Lynam, {Jason M.} and Macgregor, {Stuart A.} and Weller, {Andrew S.}",

note = "Funding: The EPSRC (EP/W015552, EP/W015498, DTP for J. C. G.), Wellcome Trust (206161/Z/17/Z); ARCHER2 UK National Supercomputing Service, Royal Society (J. M. L. INF\R1\221057). ",

year = "2023",

month = sep,

day = "16",

doi = "10.1039/d3cc03201a",

language = "English",

volume = "59",

pages = "10749--10752",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "72",

}

TY - JOUR

T1 - In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

AU - Goodall, Joe C.

AU - Sajjad, M. Arif

AU - Thompson, Emily A.

AU - Page, Samuel J.

AU - Kerrigan, Adam M.

AU - Jenkins, Huw T.

AU - Lynam, Jason M.

AU - Macgregor, Stuart A.

AU - Weller, Andrew S.

N1 - Funding: The EPSRC (EP/W015552, EP/W015498, DTP for J. C. G.), Wellcome Trust (206161/Z/17/Z); ARCHER2 UK National Supercomputing Service, Royal Society (J. M. L. INF\R1\221057).

PY - 2023/9/16

Y1 - 2023/9/16

N2 - The group 7 complexes [M(κ3-2,6-(R2PO)2C5H3N)(CO)2L][BArF4] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BArF4] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.

AB - The group 7 complexes [M(κ3-2,6-(R2PO)2C5H3N)(CO)2L][BArF4] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BArF4] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.

U2 - 10.1039/d3cc03201a

DO - 10.1039/d3cc03201a

M3 - Article

C2 - 37602809

SN - 1359-7345

VL - 59

SP - 10749

EP - 10752

JO - Chemical Communications

JF - Chemical Communications

IS - 72

ER -

In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

Abstract

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Datasets

CCDC 2271683 - 2271688 & 2271690: Experimental Crystal Structure Determination

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