Hydrothermal synthesis of polymeric metal carboxylates from benzene-1,2,4,5-tetracarboxylic acid and benzene-1,2,4-tricarboxylic acid

MJ Plater; MRS Foreman; RA Howie; JMS Skakle; Alexandra Martha Zoya Slawin

Hydrothermal synthesis of polymeric metal carboxylates from benzene-1,2,4,5-tetracarboxylic acid and benzene-1,2,4-tricarboxylic acid

MJ Plater
, MRS Foreman
, RA Howie
, JMS Skakle
, Alexandra Martha Zoya Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal-ions Co, Mn or Zn and 2,2-bipyridyl gives coordination solids of composition [Co-2(C10H2O8)(C10H8N2)(2)(H2O)] (1), [Co-3(C9H3O6)(2)(C10H8N2)(2)-(H2O)(2)] (2), [Mn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (3) or [Zn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (4). Each has a sheet structure with a distorted octahedral coordination environment. (C) 2001 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	126-132
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	315
Publication status	Published - 16 Apr 2001

Keywords

hydrothermal
coordination polymers
CRystal engineering
BENZENE-1,3,5-TRICARBOXYLIC ACID
FRAMEWORK

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@article{74dca24c0ba64e84a623b102ed299a10,

title = "Hydrothermal synthesis of polymeric metal carboxylates from benzene-1,2,4,5-tetracarboxylic acid and benzene-1,2,4-tricarboxylic acid",

abstract = "Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal-ions Co, Mn or Zn and 2,2-bipyridyl gives coordination solids of composition [Co-2(C10H2O8)(C10H8N2)(2)(H2O)] (1), [Co-3(C9H3O6)(2)(C10H8N2)(2)-(H2O)(2)] (2), [Mn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (3) or [Zn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (4). Each has a sheet structure with a distorted octahedral coordination environment. (C) 2001 Elsevier Science B.V. All rights reserved.",

keywords = "hydrothermal, coordination polymers, CRystal engineering, BENZENE-1,3,5-TRICARBOXYLIC ACID, FRAMEWORK",

author = "MJ Plater and MRS Foreman and RA Howie and JMS Skakle and Slawin, \{Alexandra Martha Zoya\}",

year = "2001",

month = apr,

day = "16",

language = "English",

volume = "315",

pages = "126--132",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

TY - JOUR

T1 - Hydrothermal synthesis of polymeric metal carboxylates from benzene-1,2,4,5-tetracarboxylic acid and benzene-1,2,4-tricarboxylic acid

AU - Plater, MJ

AU - Foreman, MRS

AU - Howie, RA

AU - Skakle, JMS

AU - Slawin, Alexandra Martha Zoya

PY - 2001/4/16

Y1 - 2001/4/16

N2 - Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal-ions Co, Mn or Zn and 2,2-bipyridyl gives coordination solids of composition [Co-2(C10H2O8)(C10H8N2)(2)(H2O)] (1), [Co-3(C9H3O6)(2)(C10H8N2)(2)-(H2O)(2)] (2), [Mn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (3) or [Zn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (4). Each has a sheet structure with a distorted octahedral coordination environment. (C) 2001 Elsevier Science B.V. All rights reserved.

AB - Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal-ions Co, Mn or Zn and 2,2-bipyridyl gives coordination solids of composition [Co-2(C10H2O8)(C10H8N2)(2)(H2O)] (1), [Co-3(C9H3O6)(2)(C10H8N2)(2)-(H2O)(2)] (2), [Mn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (3) or [Zn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (4). Each has a sheet structure with a distorted octahedral coordination environment. (C) 2001 Elsevier Science B.V. All rights reserved.

KW - hydrothermal

KW - coordination polymers

KW - CRystal engineering

KW - BENZENE-1,3,5-TRICARBOXYLIC ACID

KW - FRAMEWORK

UR - https://www.scopus.com/pages/publications/0035897098

M3 - Article

SN - 0020-1693

VL - 315

SP - 126

EP - 132

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Hydrothermal synthesis of polymeric metal carboxylates from benzene-1,2,4,5-tetracarboxylic acid and benzene-1,2,4-tricarboxylic acid

Abstract

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