Hydrolysis, oxidation and complexation: the reactions of tin(II) chloride with a tripodal Schiff base ligand

J  Parr; A T  Ross; A M Z  Slawin

Hydrolysis, oxidation and complexation: the reactions of tin(II) chloride with a tripodal Schiff base ligand

J Parr, A T Ross, A M Z Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

The interaction of SnCl2. 2H(2)O and the heptadentate tripodal Schiff base saltren yields in moderate yield the hexacoordinate Sn(IV) complex [Sn(saltren)] Cl (1). In addition, there is extensive destruction of the ligand, yielding the component triamine and aldehydes. The crystal structure of [Sn(saltren)]Cl . (salicylaldehyde) (1 . (sal)), is reported. (C) 1998 Elsevier Science S.A. All rights reserved.

Original language	English
Pages (from-to)	159-160
Number of pages	2
Journal	Inorganic Chemistry Communications
Volume	1
Issue number	5
Publication status	Published - May 1998

Keywords

crystal structures
tin complexes
Schiff base complexes
COPPER(II)
CRYSTAL

Cite this

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title = "Hydrolysis, oxidation and complexation: the reactions of tin(II) chloride with a tripodal Schiff base ligand",

abstract = "The interaction of SnCl2. 2H(2)O and the heptadentate tripodal Schiff base saltren yields in moderate yield the hexacoordinate Sn(IV) complex [Sn(saltren)] Cl (1). In addition, there is extensive destruction of the ligand, yielding the component triamine and aldehydes. The crystal structure of [Sn(saltren)]Cl . (salicylaldehyde) (1 . (sal)), is reported. (C) 1998 Elsevier Science S.A. All rights reserved.",

keywords = "crystal structures, tin complexes, Schiff base complexes, COPPER(II), CRYSTAL",

author = "J Parr and Ross, {A T} and Slawin, {A M Z}",

year = "1998",

month = may,

language = "English",

volume = "1",

pages = "159--160",

journal = "Inorganic Chemistry Communications",

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TY - JOUR

T1 - Hydrolysis, oxidation and complexation: the reactions of tin(II) chloride with a tripodal Schiff base ligand

AU - Parr, J

AU - Ross, A T

AU - Slawin, A M Z

PY - 1998/5

Y1 - 1998/5

N2 - The interaction of SnCl2. 2H(2)O and the heptadentate tripodal Schiff base saltren yields in moderate yield the hexacoordinate Sn(IV) complex [Sn(saltren)] Cl (1). In addition, there is extensive destruction of the ligand, yielding the component triamine and aldehydes. The crystal structure of [Sn(saltren)]Cl . (salicylaldehyde) (1 . (sal)), is reported. (C) 1998 Elsevier Science S.A. All rights reserved.

AB - The interaction of SnCl2. 2H(2)O and the heptadentate tripodal Schiff base saltren yields in moderate yield the hexacoordinate Sn(IV) complex [Sn(saltren)] Cl (1). In addition, there is extensive destruction of the ligand, yielding the component triamine and aldehydes. The crystal structure of [Sn(saltren)]Cl . (salicylaldehyde) (1 . (sal)), is reported. (C) 1998 Elsevier Science S.A. All rights reserved.

KW - crystal structures

KW - tin complexes

KW - Schiff base complexes

KW - COPPER(II)

KW - CRYSTAL

M3 - Article

SN - 1387-7003

VL - 1

SP - 159

EP - 160

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 5

ER -

Hydrolysis, oxidation and complexation: the reactions of tin(II) chloride with a tripodal Schiff base ligand

Abstract

Keywords

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