Hydrogenation of C-C Multiple Bonds Mediated by [Pd(NHC)(PCy3)] (NHC=N-Heterocyclic Carbene) under Mild Reaction Conditions

Vaclav Jurcik; Steven Patrick Nolan; Catherine S.J. Cazin

doi:10.1002/chem.200802412

Hydrogenation of C-C Multiple Bonds Mediated by [Pd(NHC)(PCy3)] (NHC=N-Heterocyclic Carbene) under Mild Reaction Conditions

Vaclav Jurcik, Steven Patrick Nolan, Catherine S.J. Cazin

Research output: Contribution to journal › Article › peer-review

Abstract

N-Heterocyclic carbenes do it again! [Pd(SIPr)(PCy3)] (1; SIPr=N,N′-(bis(2,6-diisopropylphenyl)imidazolidine), which is stable under H2, was shown to be a highly active catalyst for the hydrogenation of a wide range of alkenes and alkynes. Reactions proceed under mild conditions (relatively low Pd loading, RT, low pressures of H2) even when sterically hindered alkenes (tri- and tetra-substituted) are used.

Original language	English
Pages (from-to)	2509-2511
Number of pages	3
Journal	Chemistry - A European Journal
Volume	15
Issue number	11
Early online date	6 Feb 2009
DOIs	https://doi.org/10.1002/chem.200802412
Publication status	Published - 2 Mar 2009

Keywords

alkenes
homogeneous catalysis
hydrogenation
N-heterocyclic carbenes
palladium
PALLADIUM(0) COMPLEXES
CATALYSTS
OLEFINS
ROUTE

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10.1002/chem.200802412

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abstract = "N-Heterocyclic carbenes do it again! [Pd(SIPr)(PCy3)] (1; SIPr=N,N′-(bis(2,6-diisopropylphenyl)imidazolidine), which is stable under H2, was shown to be a highly active catalyst for the hydrogenation of a wide range of alkenes and alkynes. Reactions proceed under mild conditions (relatively low Pd loading, RT, low pressures of H2) even when sterically hindered alkenes (tri- and tetra-substituted) are used.",

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author = "Vaclav Jurcik and Nolan, \{Steven Patrick\} and Cazin, \{Catherine S.J.\}",

year = "2009",

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doi = "10.1002/chem.200802412",

language = "English",

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T1 - Hydrogenation of C-C Multiple Bonds Mediated by [Pd(NHC)(PCy3)] (NHC=N-Heterocyclic Carbene) under Mild Reaction Conditions

AU - Jurcik, Vaclav

AU - Nolan, Steven Patrick

AU - Cazin, Catherine S.J.

PY - 2009/3/2

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N2 - N-Heterocyclic carbenes do it again! [Pd(SIPr)(PCy3)] (1; SIPr=N,N′-(bis(2,6-diisopropylphenyl)imidazolidine), which is stable under H2, was shown to be a highly active catalyst for the hydrogenation of a wide range of alkenes and alkynes. Reactions proceed under mild conditions (relatively low Pd loading, RT, low pressures of H2) even when sterically hindered alkenes (tri- and tetra-substituted) are used.

AB - N-Heterocyclic carbenes do it again! [Pd(SIPr)(PCy3)] (1; SIPr=N,N′-(bis(2,6-diisopropylphenyl)imidazolidine), which is stable under H2, was shown to be a highly active catalyst for the hydrogenation of a wide range of alkenes and alkynes. Reactions proceed under mild conditions (relatively low Pd loading, RT, low pressures of H2) even when sterically hindered alkenes (tri- and tetra-substituted) are used.

KW - alkenes

KW - homogeneous catalysis

KW - hydrogenation

KW - N-heterocyclic carbenes

KW - palladium

KW - PALLADIUM(0) COMPLEXES

KW - CATALYSTS

KW - OLEFINS

KW - ROUTE

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U2 - 10.1002/chem.200802412

DO - 10.1002/chem.200802412

M3 - Article

SN - 0947-6539

VL - 15

SP - 2509

EP - 2511

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 11

ER -

Hydrogenation of C-C Multiple Bonds Mediated by [Pd(NHC)(PCy3)] (NHC=N-Heterocyclic Carbene) under Mild Reaction Conditions

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Keywords

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