Hydrogenation of Aldehydes, Esters, Imines, and Ketones Catalyzed by a Ruthenium Complex of a Chiral Tridentate Ligand.

Matthew L Clarke; Alexandra Martha Zoya Slawin; M B Diaz-Valenzuela

doi:10.1021/om060673b

Hydrogenation of Aldehydes, Esters, Imines, and Ketones Catalyzed by a Ruthenium Complex of a Chiral Tridentate Ligand.

Matthew L Clarke, Alexandra Martha Zoya Slawin, M B Diaz-Valenzuela

Research output: Contribution to journal › Article › peer-review

Abstract

A novel ruthenium complex prepared from a chiral tridentate amine functionalized phosphine has been characterized by X-ray crystallography and been found to be active in the hydrogenation of an unprecedented range of CO and CN double bonds, including the enantioselective hydrogenation and transfer hydrogenation of normally unreactive bulky ketones with up to 90% ee.

Original language	English
Pages (from-to)	16-19
Number of pages	4
Journal	Organometallics
Volume	26
Issue number	1
DOIs	https://doi.org/10.1021/om060673b
Publication status	Published - 1 Jan 2007

Keywords

ASYMMETRIC TRANSFER HYDROGENATION
ALPHA,BETA-UNSATURATED ALDEHYDES
ENANTIOSELECTIVE HYDROGENATION
HYDRIDE COMPLEXES
AROMATIC KETONES
STEREOSELECTIVE HYDROGENATION
SELECTIVE HYDROGENATION
DIMETHYL OXALATE
ETHYLENE-GLYCOL
ACID ESTERS

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title = "Hydrogenation of Aldehydes, Esters, Imines, and Ketones Catalyzed by a Ruthenium Complex of a Chiral Tridentate Ligand.",

abstract = "A novel ruthenium complex prepared from a chiral tridentate amine functionalized phosphine has been characterized by X-ray crystallography and been found to be active in the hydrogenation of an unprecedented range of CO and CN double bonds, including the enantioselective hydrogenation and transfer hydrogenation of normally unreactive bulky ketones with up to 90% ee.",

keywords = "ASYMMETRIC TRANSFER HYDROGENATION, ALPHA,BETA-UNSATURATED ALDEHYDES, ENANTIOSELECTIVE HYDROGENATION, HYDRIDE COMPLEXES, AROMATIC KETONES, STEREOSELECTIVE HYDROGENATION, SELECTIVE HYDROGENATION, DIMETHYL OXALATE, ETHYLENE-GLYCOL, ACID ESTERS",

author = "Clarke, {Matthew L} and Slawin, {Alexandra Martha Zoya} and Diaz-Valenzuela, {M B}",

year = "2007",

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doi = "10.1021/om060673b",

language = "English",

volume = "26",

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journal = "Organometallics",

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T1 - Hydrogenation of Aldehydes, Esters, Imines, and Ketones Catalyzed by a Ruthenium Complex of a Chiral Tridentate Ligand.

AU - Clarke, Matthew L

AU - Slawin, Alexandra Martha Zoya

AU - Diaz-Valenzuela, M B

PY - 2007/1/1

Y1 - 2007/1/1

N2 - A novel ruthenium complex prepared from a chiral tridentate amine functionalized phosphine has been characterized by X-ray crystallography and been found to be active in the hydrogenation of an unprecedented range of CO and CN double bonds, including the enantioselective hydrogenation and transfer hydrogenation of normally unreactive bulky ketones with up to 90% ee.

AB - A novel ruthenium complex prepared from a chiral tridentate amine functionalized phosphine has been characterized by X-ray crystallography and been found to be active in the hydrogenation of an unprecedented range of CO and CN double bonds, including the enantioselective hydrogenation and transfer hydrogenation of normally unreactive bulky ketones with up to 90% ee.

KW - ASYMMETRIC TRANSFER HYDROGENATION

KW - ALPHA,BETA-UNSATURATED ALDEHYDES

KW - ENANTIOSELECTIVE HYDROGENATION

KW - HYDRIDE COMPLEXES

KW - AROMATIC KETONES

KW - STEREOSELECTIVE HYDROGENATION

KW - SELECTIVE HYDROGENATION

KW - DIMETHYL OXALATE

KW - ETHYLENE-GLYCOL

KW - ACID ESTERS

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U2 - 10.1021/om060673b

DO - 10.1021/om060673b

M3 - Article

SN - 0276-7333

VL - 26

SP - 16

EP - 19

JO - Organometallics

JF - Organometallics

IS - 1

ER -

Hydrogenation of Aldehydes, Esters, Imines, and Ketones Catalyzed by a Ruthenium Complex of a Chiral Tridentate Ligand.

Abstract

Keywords

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