Hydrogen bonding in substituted nitroanilines: hydrogen-bonded sheets in 4-iodo-3-nitroaniline

SJ Garden; JL Wardell; JMS Skakle; JN Low; Christopher Glidewell

doi:10.1107/S0108270104006092

Hydrogen bonding in substituted nitroanilines: hydrogen-bonded sheets in 4-iodo-3-nitroaniline

SJ Garden
, JL Wardell
, JMS Skakle
, JN Low
, Christopher Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C6H5IN2O2, the nitro group is disordered over two sets of sites, each with 0.5 occupancy, and the amino N atom is pyramidal. The molecules are linked into sheets by a combination of three-centre N-H...(O)(2) hydrogen bonds involving alternative pairs of O-atom sites and two-centre N-H...N hydrogen bonds involving the pyramidal amino group.

Original language	English
Pages (from-to)	o328-o330
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	C60
DOIs	https://doi.org/10.1107/S0108270104006092
Publication status	Published - May 2004

Keywords

PI-STACKING INTERACTIONS
INTERPLAY

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title = "Hydrogen bonding in substituted nitroanilines: hydrogen-bonded sheets in 4-iodo-3-nitroaniline",

abstract = "In the title compound, C6H5IN2O2, the nitro group is disordered over two sets of sites, each with 0.5 occupancy, and the amino N atom is pyramidal. The molecules are linked into sheets by a combination of three-centre N-H...(O)(2) hydrogen bonds involving alternative pairs of O-atom sites and two-centre N-H...N hydrogen bonds involving the pyramidal amino group.",

keywords = "PI-STACKING INTERACTIONS, INTERPLAY",

author = "SJ Garden and JL Wardell and JMS Skakle and JN Low and Christopher Glidewell",

year = "2004",

month = may,

doi = "10.1107/S0108270104006092",

language = "English",

volume = "C60",

pages = "o328--o330",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Hydrogen bonding in substituted nitroanilines: hydrogen-bonded sheets in 4-iodo-3-nitroaniline

AU - Garden, SJ

AU - Wardell, JL

AU - Skakle, JMS

AU - Low, JN

AU - Glidewell, Christopher

PY - 2004/5

Y1 - 2004/5

N2 - In the title compound, C6H5IN2O2, the nitro group is disordered over two sets of sites, each with 0.5 occupancy, and the amino N atom is pyramidal. The molecules are linked into sheets by a combination of three-centre N-H...(O)(2) hydrogen bonds involving alternative pairs of O-atom sites and two-centre N-H...N hydrogen bonds involving the pyramidal amino group.

AB - In the title compound, C6H5IN2O2, the nitro group is disordered over two sets of sites, each with 0.5 occupancy, and the amino N atom is pyramidal. The molecules are linked into sheets by a combination of three-centre N-H...(O)(2) hydrogen bonds involving alternative pairs of O-atom sites and two-centre N-H...N hydrogen bonds involving the pyramidal amino group.

KW - PI-STACKING INTERACTIONS

KW - INTERPLAY

U2 - 10.1107/S0108270104006092

DO - 10.1107/S0108270104006092

M3 - Article

SN - 0108-2701

VL - C60

SP - o328-o330

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -

Hydrogen bonding in substituted nitroanilines: hydrogen-bonded sheets in 4-iodo-3-nitroaniline

Abstract

Keywords

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