Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline

C  Glidewell; J N  Low; S A  McWilliam; J M S  Skakle; J L  Wardell

doi:10.1107/S0108270101021485

Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline

C Glidewell, J N Low, S A McWilliam, J M S Skakle, J L Wardell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	58
DOIs	https://doi.org/10.1107/S0108270101021485
Publication status	Published - Feb 2002

Keywords

CRYSTAL

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10.1107/S0108270101021485

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title = "Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline",

abstract = "Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.",

keywords = "CRYSTAL",

author = "C Glidewell and Low, \{J N\} and McWilliam, \{S A\} and Skakle, \{J M S\} and Wardell, \{J L\}",

year = "2002",

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doi = "10.1107/S0108270101021485",

language = "English",

volume = "58",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

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publisher = "International Union of Crystallography",

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T1 - Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline

AU - Glidewell, C

AU - Low, J N

AU - McWilliam, S A

AU - Skakle, J M S

AU - Wardell, J L

PY - 2002/2

Y1 - 2002/2

N2 - Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.

AB - Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.

KW - CRYSTAL

UR - https://www.scopus.com/pages/publications/0036486972

U2 - 10.1107/S0108270101021485

DO - 10.1107/S0108270101021485

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 58

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline

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