Hydrogen-bonded sheets in racemic cis-(2,2 '-bipyridyl-kappa N-2,N ')oxo-(pentane-2,4-dionato-kappa O-2,O ')-(thio-cyanato-kappa N)vanadium(IV)

S J  Kavitha; K  Panchanatheswaran; J N  Low; C  Glidewell

doi:10.1107/S0108270106008158

Hydrogen-bonded sheets in racemic cis-(2,2 '-bipyridyl-kappa N-2,N ')oxo-(pentane-2,4-dionato-kappa O-2,O ')-(thio-cyanato-kappa N)vanadium(IV)

S J Kavitha, K Panchanatheswaran, J N Low, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [V(C5H7O2)(NCS)O(C10H8N2)], crystallizes with Z' = 2 in the space group Pbca. The mol-ecules are linked into sheets by a combination of four C-H center dot center dot center dot O hydrogen bonds and one C-H center dot center dot center dot N hydrogen bond. The four C-H center dot center dot center dot O hydrogen bonds generate chains of rings, where each chain contains just a single enanti-omer of each of the two independent mol-ecules, while the C-HcN hydrogen bond generates a chain containing both enanti-omers of just one of the independent molecules.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	62
DOIs	https://doi.org/10.1107/S0108270106008158
Publication status	Published - May 2006

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PERCHLORATE

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title = "Hydrogen-bonded sheets in racemic cis-(2,2 '-bipyridyl-kappa N-2,N ')oxo-(pentane-2,4-dionato-kappa O-2,O ')-(thio-cyanato-kappa N)vanadium(IV)",

abstract = "The title compound, [V(C5H7O2)(NCS)O(C10H8N2)], crystallizes with Z' = 2 in the space group Pbca. The mol-ecules are linked into sheets by a combination of four C-H center dot center dot center dot O hydrogen bonds and one C-H center dot center dot center dot N hydrogen bond. The four C-H center dot center dot center dot O hydrogen bonds generate chains of rings, where each chain contains just a single enanti-omer of each of the two independent mol-ecules, while the C-HcN hydrogen bond generates a chain containing both enanti-omers of just one of the independent molecules.",

keywords = "PERCHLORATE",

author = "Kavitha, {S J} and K Panchanatheswaran and Low, {J N} and C Glidewell",

year = "2006",

month = may,

doi = "10.1107/S0108270106008158",

language = "English",

volume = "62",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Hydrogen-bonded sheets in racemic cis-(2,2 '-bipyridyl-kappa N-2,N ')oxo-(pentane-2,4-dionato-kappa O-2,O ')-(thio-cyanato-kappa N)vanadium(IV)

AU - Kavitha, S J

AU - Panchanatheswaran, K

AU - Low, J N

AU - Glidewell, C

PY - 2006/5

Y1 - 2006/5

N2 - The title compound, [V(C5H7O2)(NCS)O(C10H8N2)], crystallizes with Z' = 2 in the space group Pbca. The mol-ecules are linked into sheets by a combination of four C-H center dot center dot center dot O hydrogen bonds and one C-H center dot center dot center dot N hydrogen bond. The four C-H center dot center dot center dot O hydrogen bonds generate chains of rings, where each chain contains just a single enanti-omer of each of the two independent mol-ecules, while the C-HcN hydrogen bond generates a chain containing both enanti-omers of just one of the independent molecules.

AB - The title compound, [V(C5H7O2)(NCS)O(C10H8N2)], crystallizes with Z' = 2 in the space group Pbca. The mol-ecules are linked into sheets by a combination of four C-H center dot center dot center dot O hydrogen bonds and one C-H center dot center dot center dot N hydrogen bond. The four C-H center dot center dot center dot O hydrogen bonds generate chains of rings, where each chain contains just a single enanti-omer of each of the two independent mol-ecules, while the C-HcN hydrogen bond generates a chain containing both enanti-omers of just one of the independent molecules.

KW - PERCHLORATE

U2 - 10.1107/S0108270106008158

DO - 10.1107/S0108270106008158

M3 - Article

SN - 1600-5759

VL - 62

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Hydrogen-bonded sheets in racemic cis-(2,2 '-bipyridyl-kappa N-2,N ')oxo-(pentane-2,4-dionato-kappa O-2,O ')-(thio-cyanato-kappa N)vanadium(IV)

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