TY - JOUR
T1 - Hydrogen-bonded adducts of ferrocene-1,1'-diylbis(diphenylmethanol): monomeric and polymeric adducts with 1,2-bis(4'-pyridyl)ethene and 1,6-diaminohexane
AU - Zakaria, C M
AU - Ferguson, G
AU - Lough, A J
AU - Glidewell, C
PY - 2002/1
Y1 - 2002/1
N2 - In the adduct ferrocene-1,1'-diylbis(diphenylmethanol)-1,2-bis(4-pyridyl)ethene (1/1), [Fe(C18H15O)(2)].C12H10N2, there is an intramolecular O-H...O hydrogen bond in the ferrocenediol component and a single O-H...N hydrogen bond linking the diol to the diamine, which is disordered over two sets of sites, so forming a finite monomeric adduct. In the adduct ferrocene-1,1'-diylbis(diphenylmethanol)-1,6-diamino-hexane (2/1), 2[Fe(C18H15O)(2)].C6H16N2, the amine lies across a centre of inversion in space group P (1) over bar. There is an intramolecular O-H...O hydrogen bond in the ferrocenediol, and the molecular components are linked by O-H...N and N-H...O hydrogen bonds, one of each type, into a C-3(3)(13)[R-6(6)(12)] chain of rings.
AB - In the adduct ferrocene-1,1'-diylbis(diphenylmethanol)-1,2-bis(4-pyridyl)ethene (1/1), [Fe(C18H15O)(2)].C12H10N2, there is an intramolecular O-H...O hydrogen bond in the ferrocenediol component and a single O-H...N hydrogen bond linking the diol to the diamine, which is disordered over two sets of sites, so forming a finite monomeric adduct. In the adduct ferrocene-1,1'-diylbis(diphenylmethanol)-1,6-diamino-hexane (2/1), 2[Fe(C18H15O)(2)].C6H16N2, the amine lies across a centre of inversion in space group P (1) over bar. There is an intramolecular O-H...O hydrogen bond in the ferrocenediol, and the molecular components are linked by O-H...N and N-H...O hydrogen bonds, one of each type, into a C-3(3)(13)[R-6(6)(12)] chain of rings.
KW - MOLECULAR-STRUCTURES
KW - CRYSTAL
U2 - 10.1107/S0108270101017152
DO - 10.1107/S0108270101017152
M3 - Article
SN - 0108-2701
VL - 58
SP - m1-m4
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
ER -