Abstract
P(OPh)(3), P(OC6H4-4-C9H19)(3) (1) and Ph2PCH2CH(CO2C16H33)CH2CO2C16H33 (2) provide rhodium catalysts which are insoluble in scCO(2) but which can show high activity and selectivity in the hydroformylation of hex-1-ene; removing the products from the reaction by flushing them into a second autoclave and decompressing gives the aldehyde product containing undetectable amounts of rhodium and the catalyst can be reused several times.
| Original language | English |
|---|---|
| Pages (from-to) | 1681-1683 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Dalton Transactions |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 2000 |
Keywords
- PHASE-TRANSFER CATALYSIS
- RHODIUM CATALYST
- METHYL FORMATE
- HYDROGENATION
- N,N-DIMETHYLFORMAMIDE
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