Hydroformylation reactions in supercritical carbon dioxide using insoluble metal complexes

MF Sellin; David John Cole-Hamilton

doi:10.1039/b001317j

Hydroformylation reactions in supercritical carbon dioxide using insoluble metal complexes

Research output: Contribution to journal › Article › peer-review

Abstract

P(OPh)(3), P(OC6H4-4-C9H19)(3) (1) and Ph2PCH2CH(CO2C16H33)CH2CO2C16H33 (2) provide rhodium catalysts which are insoluble in scCO(2) but which can show high activity and selectivity in the hydroformylation of hex-1-ene; removing the products from the reaction by flushing them into a second autoclave and decompressing gives the aldehyde product containing undetectable amounts of rhodium and the catalyst can be reused several times.

Original language	English
Pages (from-to)	1681-1683
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	11
DOIs	https://doi.org/10.1039/b001317j
Publication status	Published - 2000

Keywords

PHASE-TRANSFER CATALYSIS
RHODIUM CATALYST
METHYL FORMATE
HYDROGENATION
N,N-DIMETHYLFORMAMIDE

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10.1039/b001317j

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title = "Hydroformylation reactions in supercritical carbon dioxide using insoluble metal complexes",

abstract = "P(OPh)(3), P(OC6H4-4-C9H19)(3) (1) and Ph2PCH2CH(CO2C16H33)CH2CO2C16H33 (2) provide rhodium catalysts which are insoluble in scCO(2) but which can show high activity and selectivity in the hydroformylation of hex-1-ene; removing the products from the reaction by flushing them into a second autoclave and decompressing gives the aldehyde product containing undetectable amounts of rhodium and the catalyst can be reused several times.",

keywords = "PHASE-TRANSFER CATALYSIS, RHODIUM CATALYST, METHYL FORMATE, HYDROGENATION, N,N-DIMETHYLFORMAMIDE",

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year = "2000",

doi = "10.1039/b001317j",

language = "English",

pages = "1681--1683",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Hydroformylation reactions in supercritical carbon dioxide using insoluble metal complexes

AU - Sellin, MF

AU - Cole-Hamilton, David John

PY - 2000

Y1 - 2000

N2 - P(OPh)(3), P(OC6H4-4-C9H19)(3) (1) and Ph2PCH2CH(CO2C16H33)CH2CO2C16H33 (2) provide rhodium catalysts which are insoluble in scCO(2) but which can show high activity and selectivity in the hydroformylation of hex-1-ene; removing the products from the reaction by flushing them into a second autoclave and decompressing gives the aldehyde product containing undetectable amounts of rhodium and the catalyst can be reused several times.

AB - P(OPh)(3), P(OC6H4-4-C9H19)(3) (1) and Ph2PCH2CH(CO2C16H33)CH2CO2C16H33 (2) provide rhodium catalysts which are insoluble in scCO(2) but which can show high activity and selectivity in the hydroformylation of hex-1-ene; removing the products from the reaction by flushing them into a second autoclave and decompressing gives the aldehyde product containing undetectable amounts of rhodium and the catalyst can be reused several times.

KW - PHASE-TRANSFER CATALYSIS

KW - RHODIUM CATALYST

KW - METHYL FORMATE

KW - HYDROGENATION

KW - N,N-DIMETHYLFORMAMIDE

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U2 - 10.1039/b001317j

DO - 10.1039/b001317j

M3 - Article

SN - 0300-9246

SP - 1681

EP - 1683

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 11

ER -

Hydroformylation reactions in supercritical carbon dioxide using insoluble metal complexes

Abstract

Keywords

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