Hydroformylation in fluorous solvents

Dave J Adams, David John Cole-Hamilton, Eric G Hope, Peter J Pogorzelec, Alison M Stuart

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

The hydroformylation of long chain alkenes under fluorous biphase conditions and in neat perfluorocarbon solvents is reviewed. Special emphasis is placed upon the authors' evaluation of the steric and electronic influence of perfluoroalkylation on catalyst activity. regioselectivity and retention in the fluorocarbon phase. (C) 2004 Elsevier B.V. All rights reserved.

Original languageEnglish
Pages (from-to)1413-1417
Number of pages5
JournalJournal of Organometallic Chemistry
Volume689
Issue number8
DOIs
Publication statusPublished - 15 Apr 2004

Keywords

  • fluorous
  • hydroformylation
  • rhodium
  • phosphine
  • CATALYST SEPARATION
  • BIPHASIC CATALYSIS
  • COMPLEXES
  • LIGANDS
  • SYSTEM
  • TRIARYLPHOSPHINES
  • PONYTAILS
  • CHEMISTRY
  • ALKENES
  • OLEFINS

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