Hydroformylation in fluorous solvents

Dave J Adams; David John Cole-Hamilton; Eric G Hope; Peter J Pogorzelec; Alison M Stuart

doi:10.1016/j.jorganchem.2004.02.010

Hydroformylation in fluorous solvents

Dave J Adams, David John Cole-Hamilton, Eric G Hope, Peter J Pogorzelec, Alison M Stuart

Research output: Contribution to journal › Article › peer-review

Abstract

The hydroformylation of long chain alkenes under fluorous biphase conditions and in neat perfluorocarbon solvents is reviewed. Special emphasis is placed upon the authors' evaluation of the steric and electronic influence of perfluoroalkylation on catalyst activity. regioselectivity and retention in the fluorocarbon phase. (C) 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1413-1417
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	689
Issue number	8
DOIs	https://doi.org/10.1016/j.jorganchem.2004.02.010
Publication status	Published - 15 Apr 2004

Keywords

fluorous
hydroformylation
rhodium
phosphine
CATALYST SEPARATION
BIPHASIC CATALYSIS
COMPLEXES
LIGANDS
SYSTEM
TRIARYLPHOSPHINES
PONYTAILS
CHEMISTRY
ALKENES
OLEFINS

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10.1016/j.jorganchem.2004.02.010

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title = "Hydroformylation in fluorous solvents",

abstract = "The hydroformylation of long chain alkenes under fluorous biphase conditions and in neat perfluorocarbon solvents is reviewed. Special emphasis is placed upon the authors' evaluation of the steric and electronic influence of perfluoroalkylation on catalyst activity. regioselectivity and retention in the fluorocarbon phase. (C) 2004 Elsevier B.V. All rights reserved.",

keywords = "fluorous, hydroformylation, rhodium, phosphine, CATALYST SEPARATION, BIPHASIC CATALYSIS, COMPLEXES, LIGANDS, SYSTEM, TRIARYLPHOSPHINES, PONYTAILS, CHEMISTRY, ALKENES, OLEFINS",

author = "Adams, {Dave J} and Cole-Hamilton, {David John} and Hope, {Eric G} and Pogorzelec, {Peter J} and Stuart, {Alison M}",

year = "2004",

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doi = "10.1016/j.jorganchem.2004.02.010",

language = "English",

volume = "689",

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journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - Hydroformylation in fluorous solvents

AU - Adams, Dave J

AU - Cole-Hamilton, David John

AU - Hope, Eric G

AU - Pogorzelec, Peter J

AU - Stuart, Alison M

PY - 2004/4/15

Y1 - 2004/4/15

N2 - The hydroformylation of long chain alkenes under fluorous biphase conditions and in neat perfluorocarbon solvents is reviewed. Special emphasis is placed upon the authors' evaluation of the steric and electronic influence of perfluoroalkylation on catalyst activity. regioselectivity and retention in the fluorocarbon phase. (C) 2004 Elsevier B.V. All rights reserved.

AB - The hydroformylation of long chain alkenes under fluorous biphase conditions and in neat perfluorocarbon solvents is reviewed. Special emphasis is placed upon the authors' evaluation of the steric and electronic influence of perfluoroalkylation on catalyst activity. regioselectivity and retention in the fluorocarbon phase. (C) 2004 Elsevier B.V. All rights reserved.

KW - fluorous

KW - hydroformylation

KW - rhodium

KW - phosphine

KW - CATALYST SEPARATION

KW - BIPHASIC CATALYSIS

KW - COMPLEXES

KW - LIGANDS

KW - SYSTEM

KW - TRIARYLPHOSPHINES

KW - PONYTAILS

KW - CHEMISTRY

KW - ALKENES

KW - OLEFINS

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U2 - 10.1016/j.jorganchem.2004.02.010

DO - 10.1016/j.jorganchem.2004.02.010

M3 - Article

SN - 0022-328X

VL - 689

SP - 1413

EP - 1417

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 8

ER -

Hydroformylation in fluorous solvents

Abstract

Keywords

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