Hybrid charged heterometallic Pt-Ir complexes: tailoring excited states by taking the best of both worlds

Ahmed M. Soliman; Daniel Fortin; Pierre D. Harvey; Eli Zysman-Colman

doi:10.1039/c1cc15507e

Hybrid charged heterometallic Pt-Ir complexes: tailoring excited states by taking the best of both worlds

Ahmed M. Soliman, Daniel Fortin, Pierre D. Harvey^*, Eli Zysman-Colman

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The C C-linkage of Pt(PR(3))(2)(C CAr)(2) with (C(boolean AND)N)(2)Ir(N(boolean AND)N)(+) (C(boolean AND)N = 2-phenylpyridine; N(boolean AND)N = bipyridyl) leads to hetero-biand trimetallic species exhibiting photophysical properties reminiscent of both [Pt]- and [Ir]-containing moieties through the generation of a [Pt] > [Ir] charge transfer excited state.

Original language	English
Pages (from-to)	1120-1122
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	8
DOIs	https://doi.org/10.1039/c1cc15507e
Publication status	Published - 2012

Keywords

PHOTOPHYSICAL PROPERTIES
METAL-COMPLEXES
SOLAR-CELLS
IRIDIUM
CHROMOPHORES
OLIGOMERS
POLYMERS
DEVICES

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10.1039/c1cc15507e

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@article{494bdd8a58ab4a148e8e8db57fecabc8,

title = "Hybrid charged heterometallic Pt-Ir complexes: tailoring excited states by taking the best of both worlds",

abstract = "The C C-linkage of Pt(PR(3))(2)(C CAr)(2) with (C(boolean AND)N)(2)Ir(N(boolean AND)N)(+) (C(boolean AND)N = 2-phenylpyridine; N(boolean AND)N = bipyridyl) leads to hetero-biand trimetallic species exhibiting photophysical properties reminiscent of both [Pt]- and [Ir]-containing moieties through the generation of a [Pt] > [Ir] charge transfer excited state.",

keywords = "PHOTOPHYSICAL PROPERTIES, METAL-COMPLEXES, SOLAR-CELLS, IRIDIUM, CHROMOPHORES, OLIGOMERS, POLYMERS, DEVICES",

author = "Soliman, {Ahmed M.} and Daniel Fortin and Harvey, {Pierre D.} and Eli Zysman-Colman",

year = "2012",

doi = "10.1039/c1cc15507e",

language = "English",

volume = "48",

pages = "1120--1122",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Hybrid charged heterometallic Pt-Ir complexes: tailoring excited states by taking the best of both worlds

AU - Soliman, Ahmed M.

AU - Fortin, Daniel

AU - Harvey, Pierre D.

AU - Zysman-Colman, Eli

PY - 2012

Y1 - 2012

N2 - The C C-linkage of Pt(PR(3))(2)(C CAr)(2) with (C(boolean AND)N)(2)Ir(N(boolean AND)N)(+) (C(boolean AND)N = 2-phenylpyridine; N(boolean AND)N = bipyridyl) leads to hetero-biand trimetallic species exhibiting photophysical properties reminiscent of both [Pt]- and [Ir]-containing moieties through the generation of a [Pt] > [Ir] charge transfer excited state.

AB - The C C-linkage of Pt(PR(3))(2)(C CAr)(2) with (C(boolean AND)N)(2)Ir(N(boolean AND)N)(+) (C(boolean AND)N = 2-phenylpyridine; N(boolean AND)N = bipyridyl) leads to hetero-biand trimetallic species exhibiting photophysical properties reminiscent of both [Pt]- and [Ir]-containing moieties through the generation of a [Pt] > [Ir] charge transfer excited state.

KW - PHOTOPHYSICAL PROPERTIES

KW - METAL-COMPLEXES

KW - SOLAR-CELLS

KW - IRIDIUM

KW - CHROMOPHORES

KW - OLIGOMERS

KW - POLYMERS

KW - DEVICES

U2 - 10.1039/c1cc15507e

DO - 10.1039/c1cc15507e

M3 - Article

SN - 1359-7345

VL - 48

SP - 1120

EP - 1122

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

Hybrid charged heterometallic Pt-Ir complexes: tailoring excited states by taking the best of both worlds

Abstract

Keywords

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