Hybrid charged heterometallic Pt-Ir complexes: tailoring excited states by taking the best of both worlds

Ahmed M. Soliman, Daniel Fortin, Pierre D. Harvey*, Eli Zysman-Colman

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

The C C-linkage of Pt(PR(3))(2)(C CAr)(2) with (C(boolean AND)N)(2)Ir(N(boolean AND)N)(+) (C(boolean AND)N = 2-phenylpyridine; N(boolean AND)N = bipyridyl) leads to hetero-biand trimetallic species exhibiting photophysical properties reminiscent of both [Pt]- and [Ir]-containing moieties through the generation of a [Pt] > [Ir] charge transfer excited state.

Original languageEnglish
Pages (from-to)1120-1122
Number of pages3
JournalChemical Communications
Volume48
Issue number8
DOIs
Publication statusPublished - 2012

Keywords

  • PHOTOPHYSICAL PROPERTIES
  • METAL-COMPLEXES
  • SOLAR-CELLS
  • IRIDIUM
  • CHROMOPHORES
  • OLIGOMERS
  • POLYMERS
  • DEVICES

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