Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap

Hari Singh; John M. Tedder; John C. Walton

Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap

Hari Singh, John M. Tedder^*, John C. Walton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.

Original language	English
Pages (from-to)	1259-1261
Number of pages	3
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	8
Publication status	Published - 1 Dec 1980

Handle.net

Persistent link

Cite this

@article{0bd727f4b00b4d33a7b855de3740ab76,

title = "Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap",

abstract = "When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.",

author = "Hari Singh and Tedder, \{John M.\} and Walton, \{John C.\}",

year = "1980",

month = dec,

day = "1",

language = "English",

pages = "1259--1261",

journal = "Journal of the Chemical Society, Perkin Transactions 2",

issn = "1472-779X",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap

AU - Singh, Hari

AU - Tedder, John M.

AU - Walton, John C.

PY - 1980/12/1

Y1 - 1980/12/1

N2 - When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.

AB - When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.

UR - https://www.scopus.com/pages/publications/37049095949

M3 - Article

AN - SCOPUS:37049095949

SN - 1472-779X

SP - 1259

EP - 1261

JO - Journal of the Chemical Society, Perkin Transactions 2

JF - Journal of the Chemical Society, Perkin Transactions 2

IS - 8

ER -

Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap

Abstract

Handle.net

Other files and links

Fingerprint

Cite this