Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap

Hari Singh; John M. Tedder; John C. Walton

Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap

Hari Singh, John M. Tedder^*, John C. Walton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.

Original language	English
Pages (from-to)	1259-1261
Number of pages	3
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	8
Publication status	Published - 1 Dec 1980

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title = "Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap",

abstract = "When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.",

author = "Hari Singh and Tedder, {John M.} and Walton, {John C.}",

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AU - Tedder, John M.

AU - Walton, John C.

PY - 1980/12/1

Y1 - 1980/12/1

N2 - When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.

AB - When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.

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JO - Journal of the Chemical Society, Perkin Transactions 2

JF - Journal of the Chemical Society, Perkin Transactions 2

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Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap

Abstract

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