Homosolvolysis. Part 2. Di-t-butyl nitroxide as the solvent and 2-methyl-2-nitrosopropane as internally generated spin trap

Hari Singh, John M. Tedder*, John C. Walton

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.

Original languageEnglish
Pages (from-to)1259-1261
Number of pages3
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number8
Publication statusPublished - 1 Dec 1980

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