Homoleptic and heteroleptic bis-NHC Cu(I) complexes as carbene transfer reagents

Orlando Santoro; Faïma Lazreg; David B. Cordes; Alexandra Martha Zoya Slawin; Catherine S. J. Cazin

doi:10.1039/C6DT00595K

Homoleptic and heteroleptic bis-NHC Cu(I) complexes as carbene transfer reagents

Orlando Santoro, Faïma Lazreg, David B. Cordes, Alexandra Martha Zoya Slawin, Catherine S. J. Cazin

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Abstract

Homo- and heteroleptic bis-NHC copper(I) complexes have been efficiently used as carbene transfer reagents to Au and Pd. The simple and straightforward procedure allows for the synthesis of well-known gold complexes as well as novel cationic bis-NHC Pd(II) species.

Original language	English
Pages (from-to)	4970-4973
Number of pages	4
Journal	Dalton Transactions
Volume	45
Issue number	12
Early online date	1 Mar 2016
DOIs	https://doi.org/10.1039/C6DT00595K
Publication status	Published - 28 Mar 2016

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10.1039/C6DT00595K

Cazin_2016_DT_CarbeneTransferReagents_AM
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C6DT00595K
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Cite this

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title = "Homoleptic and heteroleptic bis-NHC Cu(I) complexes as carbene transfer reagents",

abstract = "Homo- and heteroleptic bis-NHC copper(I) complexes have been efficiently used as carbene transfer reagents to Au and Pd. The simple and straightforward procedure allows for the synthesis of well-known gold complexes as well as novel cationic bis-NHC Pd(II) species.",

author = "Orlando Santoro and Fa{\"i}ma Lazreg and Cordes, {David B.} and Slawin, {Alexandra Martha Zoya} and Cazin, {Catherine S. J.}",

note = "The authors gratefully acknowledge the Royal Society (University Research Fellowship to C. S. J. C.) and the EPSRC (DTG011 EP/J500549/1) for financial support.",

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AU - Santoro, Orlando

AU - Lazreg, Faïma

AU - Cordes, David B.

AU - Slawin, Alexandra Martha Zoya

AU - Cazin, Catherine S. J.

N1 - The authors gratefully acknowledge the Royal Society (University Research Fellowship to C. S. J. C.) and the EPSRC (DTG011 EP/J500549/1) for financial support.

PY - 2016/3/28

Y1 - 2016/3/28

N2 - Homo- and heteroleptic bis-NHC copper(I) complexes have been efficiently used as carbene transfer reagents to Au and Pd. The simple and straightforward procedure allows for the synthesis of well-known gold complexes as well as novel cationic bis-NHC Pd(II) species.

AB - Homo- and heteroleptic bis-NHC copper(I) complexes have been efficiently used as carbene transfer reagents to Au and Pd. The simple and straightforward procedure allows for the synthesis of well-known gold complexes as well as novel cationic bis-NHC Pd(II) species.

UR - http://www.rsc.org/suppdata/c6/dt/c6dt00595k/c6dt00595k1.pdf

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DO - 10.1039/C6DT00595K

M3 - Article

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SP - 4970

EP - 4973

JO - Dalton Transactions

JF - Dalton Transactions

IS - 12

ER -

Homoleptic and heteroleptic bis-NHC Cu(I) complexes as carbene transfer reagents

Abstract

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Catalytic C-H bond functionalisation: Catalytic C-H bond functionalisation