Highly Active [Pd(μ-Cl)Cl(NHC)]2 Complexes in the Mizoroki–Heck Reaction

Ulrike I. Tessin; Xavier Bantreil; Olivier Songis; Catherine S.J. Cazin

doi:10.1002/ejic.201300169

Highly Active [Pd(μ-Cl)Cl(NHC)]2 Complexes in the Mizoroki–Heck Reaction

Ulrike I. Tessin, Xavier Bantreil, Olivier Songis, Catherine S.J. Cazin

Research output: Contribution to journal › Article › peer-review

Abstract

A series of Pd dimers bearing an N-heterocyclic carbene ligand
was studied in the Mizoroki–Heck reaction. [Pd(μ-Cl)-
Cl(SIPr)]2 (SIPr = {N,N-bis[2,6-(diisopropyl)phenyl]imid-azolidin-2-ylidene}) was shown to be highly efficient in this cross-coupling for a range of aryl and heterocyclic bromides, with low palladium loading (20–200 ppm).

Original language	English
Pages (from-to)	2007-2010
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Volume	12
Early online date	18 Mar 2013
DOIs	https://doi.org/10.1002/ejic.201300169
Publication status	Published - Mar 2013

Keywords

Mizoroki–Heck reaction / Cross-coupling / Carbene ligands / Palladium

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10.1002/ejic.201300169

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title = "Highly Active [Pd(μ-Cl)Cl(NHC)]2 Complexes in the Mizoroki–Heck Reaction",

abstract = "A series of Pd dimers bearing an N-heterocyclic carbene ligand was studied in the Mizoroki–Heck reaction. [Pd(μ-Cl)- Cl(SIPr)]2 (SIPr = \{N,N-bis[2,6-(diisopropyl)phenyl]imid-azolidin-2-ylidene\}) was shown to be highly efficient in this cross-coupling for a range of aryl and heterocyclic bromides, with low palladium loading (20–200 ppm).",

keywords = "Mizoroki–Heck reaction / Cross-coupling / Carbene ligands / Palladium",

author = "Tessin, \{Ulrike I.\} and Xavier Bantreil and Olivier Songis and Cazin, \{Catherine S.J.\}",

year = "2013",

month = mar,

doi = "10.1002/ejic.201300169",

language = "English",

volume = "12",

pages = "2007--2010",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH, Weinheim",

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TY - JOUR

T1 - Highly Active [Pd(μ-Cl)Cl(NHC)]2 Complexes in the Mizoroki–Heck Reaction

AU - Tessin, Ulrike I.

AU - Bantreil, Xavier

AU - Songis, Olivier

AU - Cazin, Catherine S.J.

PY - 2013/3

Y1 - 2013/3

N2 - A series of Pd dimers bearing an N-heterocyclic carbene ligand was studied in the Mizoroki–Heck reaction. [Pd(μ-Cl)- Cl(SIPr)]2 (SIPr = {N,N-bis[2,6-(diisopropyl)phenyl]imid-azolidin-2-ylidene}) was shown to be highly efficient in this cross-coupling for a range of aryl and heterocyclic bromides, with low palladium loading (20–200 ppm).

AB - A series of Pd dimers bearing an N-heterocyclic carbene ligand was studied in the Mizoroki–Heck reaction. [Pd(μ-Cl)- Cl(SIPr)]2 (SIPr = {N,N-bis[2,6-(diisopropyl)phenyl]imid-azolidin-2-ylidene}) was shown to be highly efficient in this cross-coupling for a range of aryl and heterocyclic bromides, with low palladium loading (20–200 ppm).

KW - Mizoroki–Heck reaction / Cross-coupling / Carbene ligands / Palladium

UR - https://www.scopus.com/pages/publications/84876232669

U2 - 10.1002/ejic.201300169

DO - 10.1002/ejic.201300169

M3 - Article

SN - 1434-1948

VL - 12

SP - 2007

EP - 2010

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

ER -

Highly Active [Pd(μ-Cl)Cl(NHC)]2 Complexes in the Mizoroki–Heck Reaction

Abstract

Keywords

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Studies of homogeneous catalysts: Mechanistic studies of homogeneous catalysts

Synergistic Ligand Effects in Palladium: Synergistic Ligand Effects in Palladium Catalysis

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Highly Active [Pd(μ-Cl)Cl(NHC)]2 Complexes in the Mizoroki–Heck Reaction

Abstract

Keywords

Access to Document

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Fingerprint

Projects

Studies of homogeneous catalysts: Mechanistic studies of homogeneous catalysts

Synergistic Ligand Effects in Palladium: Synergistic Ligand Effects in Palladium Catalysis

Cite this