Highly Active [Pd(μ-Cl)Cl(NHC)]2 Complexes in the Mizoroki–Heck Reaction

Ulrike I. Tessin, Xavier Bantreil, Olivier Songis, Catherine S.J. Cazin

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)

Abstract

A series of Pd dimers bearing an N-heterocyclic carbene ligand
was studied in the Mizoroki–Heck reaction. [Pd(μ-Cl)-
Cl(SIPr)]2 (SIPr = {N,N-bis[2,6-(diisopropyl)phenyl]imid-azolidin-2-ylidene}) was shown to be highly efficient in this cross-coupling for a range of aryl and heterocyclic bromides, with low palladium loading (20–200 ppm).
Original languageEnglish
Pages (from-to)2007-2010
Number of pages4
JournalEuropean Journal of Inorganic Chemistry
Volume12
Early online date18 Mar 2013
DOIs
Publication statusPublished - Mar 2013

Keywords

  • Mizoroki–Heck reaction / Cross-coupling / Carbene ligands / Palladium

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