Highly active cobalt based catalysts for the carbonylation of methanol

AC Marr; EJ Ditzel; AC Benyei; Philip Lightfoot; David John Cole-Hamilton

Highly active cobalt based catalysts for the carbonylation of methanol

AC Marr, EJ Ditzel, AC Benyei, Philip Lightfoot, David John Cole-Hamilton

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Abstract

[Cp*Co(CO)(2)] in the presence of PEt3 and MeI catalyses the carbonylation of methanol with initial rates up to 44 mol dm(-3) h(-1) before decaying to a second catalytic phase with rates of 3 mol dm(-3) h(-1); [CoI(CO)(2)(PEt3)(2)], which is trigonal bipyramidal with axial PEt3 ligands, has been isolated from the final reaction solution.

Original language	English
Number of pages	1379
Publication status	Published - 1999

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@misc{f1af415e7ee94ac191df512a05d704be,

title = "Highly active cobalt based catalysts for the carbonylation of methanol",

abstract = "[Cp*Co(CO)(2)] in the presence of PEt3 and MeI catalyses the carbonylation of methanol with initial rates up to 44 mol dm(-3) h(-1) before decaying to a second catalytic phase with rates of 3 mol dm(-3) h(-1); [CoI(CO)(2)(PEt3)(2)], which is trigonal bipyramidal with axial PEt3 ligands, has been isolated from the final reaction solution.",

author = "AC Marr and EJ Ditzel and AC Benyei and Philip Lightfoot and Cole-Hamilton, \{David John\}",

note = "Chem Commun",

year = "1999",

language = "English",

type = "Other",

}

TY - GEN

T1 - Highly active cobalt based catalysts for the carbonylation of methanol

AU - Marr, AC

AU - Ditzel, EJ

AU - Benyei, AC

AU - Lightfoot, Philip

AU - Cole-Hamilton, David John

N1 - Chem Commun

PY - 1999

Y1 - 1999

N2 - [Cp*Co(CO)(2)] in the presence of PEt3 and MeI catalyses the carbonylation of methanol with initial rates up to 44 mol dm(-3) h(-1) before decaying to a second catalytic phase with rates of 3 mol dm(-3) h(-1); [CoI(CO)(2)(PEt3)(2)], which is trigonal bipyramidal with axial PEt3 ligands, has been isolated from the final reaction solution.

AB - [Cp*Co(CO)(2)] in the presence of PEt3 and MeI catalyses the carbonylation of methanol with initial rates up to 44 mol dm(-3) h(-1) before decaying to a second catalytic phase with rates of 3 mol dm(-3) h(-1); [CoI(CO)(2)(PEt3)(2)], which is trigonal bipyramidal with axial PEt3 ligands, has been isolated from the final reaction solution.

M3 - Other contribution

ER -

Highly active cobalt based catalysts for the carbonylation of methanol

Abstract

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