High-temperature stability study of the oxygen-ion conductor La0.9Sr0.1Ga0.8Mg0.2O3-x

S W Tao, F W Poulsen, G Y Meng, O T Sorensen

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

La0.9Sr0.1Ga0.8Mg0.2O3-x (LSGM) has been prepared by a complexing sol-gel process and characterised by X-ray diffraction, thermogravimetric-differential thermal analysis (TG-DTA) and conventional weight analysis. The room-temperature structure is orthorhombic, space group Pnma, with a = 5.5340(14), b = 5.5074(22), c = 7.8003(31) Angstrom. After heating at 1000 degrees C, the lattice parameters of LSGM shift a little, and La4SrO7 and SrLaGaO4 separate from the parent phase, which may further affect other properties. The weight change of LSGM at 750 degrees C is insignificant and the phase is also stable after heating at 750 degrees C in a hydrogen atmosphere for a total of 132 h. Defect chemistry modelling supports the view that LSGM is not single phase at 1000 degrees C.

Original languageEnglish
Pages (from-to)1829-1833
Number of pages5
JournalJournal of Materials Chemistry
Volume10
Publication statusPublished - 2000

Keywords

  • DOPED LANTHANUM GALLATE
  • PEROVSKITE-TYPE OXIDE
  • CHEMICAL-STABILITY
  • FUEL-CELLS
  • ELECTROLYTE
  • PROTON
  • LAGAO3

Fingerprint

Dive into the research topics of 'High-temperature stability study of the oxygen-ion conductor La0.9Sr0.1Ga0.8Mg0.2O3-x'. Together they form a unique fingerprint.

Cite this