High-frequency EPR of octahedral Mn(II) compounds with large zero-field splittings

D M L  Goodgame; H  El Mkami; G M  Smith; J P  Zhao; E J L  McInnes

doi:10.1039/b210407p

High-frequency EPR of octahedral Mn(II) compounds with large zero-field splittings

D M L Goodgame, H El Mkami, G M Smith, J P Zhao, E J L McInnes

School of Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

Abstract

The use of HF-EPR to determine large zero-field splittings in distorted octahedral, high-spin d(5) ions is demonstrated with two Mn(II) coordination polymers, giving detail on both electronic and geometric structure.

Original language	English
Pages (from-to)	34-35
Number of pages	2
Journal	Dalton Transactions
Issue number	1
DOIs	https://doi.org/10.1039/b210407p
Publication status	Published - 2003

Keywords

SPECTROSCOPY
SPECTRA
ION

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10.1039/b210407p

Cite this

@article{8741955af7f34374b79f6c7665ba8114,

title = "High-frequency EPR of octahedral Mn(II) compounds with large zero-field splittings",

abstract = "The use of HF-EPR to determine large zero-field splittings in distorted octahedral, high-spin d(5) ions is demonstrated with two Mn(II) coordination polymers, giving detail on both electronic and geometric structure.",

keywords = "SPECTROSCOPY, SPECTRA, ION",

author = "Goodgame, \{D M L\} and \{El Mkami\}, H and Smith, \{G M\} and Zhao, \{J P\} and McInnes, \{E J L\}",

year = "2003",

doi = "10.1039/b210407p",

language = "English",

pages = "34--35",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "1",

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T1 - High-frequency EPR of octahedral Mn(II) compounds with large zero-field splittings

AU - Goodgame, D M L

AU - El Mkami, H

AU - Smith, G M

AU - Zhao, J P

AU - McInnes, E J L

PY - 2003

Y1 - 2003

N2 - The use of HF-EPR to determine large zero-field splittings in distorted octahedral, high-spin d(5) ions is demonstrated with two Mn(II) coordination polymers, giving detail on both electronic and geometric structure.

AB - The use of HF-EPR to determine large zero-field splittings in distorted octahedral, high-spin d(5) ions is demonstrated with two Mn(II) coordination polymers, giving detail on both electronic and geometric structure.

KW - SPECTROSCOPY

KW - SPECTRA

KW - ION

UR - https://www.scopus.com/pages/publications/1642460283

U2 - 10.1039/b210407p

DO - 10.1039/b210407p

M3 - Article

SN - 1477-9226

SP - 34

EP - 35

JO - Dalton Transactions

JF - Dalton Transactions

IS - 1

ER -

High-frequency EPR of octahedral Mn(II) compounds with large zero-field splittings

Abstract

Keywords

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