High activity cobalt based catalysts for the carbonylation of methanol

Andrew C. Marr; Evert J. Ditzel; Attila C. Benyei; P. Lightfoot; David J. Cole-Hamilton

doi:10.1039/a903169c

High activity cobalt based catalysts for the carbonylation of methanol

Andrew C. Marr, Evert J. Ditzel, Attila C. Benyei, P. Lightfoot, David J. Cole-Hamilton^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

[Cp(*)Co(CO)₂] in the presence of PEt₃ and Mel catalyses the carbonylation of methanol with initial rates up to 44 mol dm^-3 h^-1 before decaying to a second catalytic phase with rates of 3 mol dm^-3 h^-1; [CoI(CO)₂(PEt₃)₂], which is trigonal bipyramidal with axial PEt₃ ligands, has been isolated from the final reaction solution.

Original language	English
Pages (from-to)	1379-1380
Number of pages	2
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/a903169c
Publication status	Published - 7 Aug 1999

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title = "High activity cobalt based catalysts for the carbonylation of methanol",

abstract = "[Cp(*)Co(CO)2] in the presence of PEt3 and Mel catalyses the carbonylation of methanol with initial rates up to 44 mol dm-3 h-1 before decaying to a second catalytic phase with rates of 3 mol dm-3 h-1; [CoI(CO)2(PEt3)2], which is trigonal bipyramidal with axial PEt3 ligands, has been isolated from the final reaction solution.",

author = "Marr, {Andrew C.} and Ditzel, {Evert J.} and Benyei, {Attila C.} and P. Lightfoot and Cole-Hamilton, {David J.}",

year = "1999",

month = aug,

day = "7",

doi = "10.1039/a903169c",

language = "English",

pages = "1379--1380",

journal = "Chemical Communications",

issn = "1359-7345",

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T1 - High activity cobalt based catalysts for the carbonylation of methanol

AU - Marr, Andrew C.

AU - Ditzel, Evert J.

AU - Benyei, Attila C.

AU - Lightfoot, P.

AU - Cole-Hamilton, David J.

PY - 1999/8/7

Y1 - 1999/8/7

N2 - [Cp(*)Co(CO)2] in the presence of PEt3 and Mel catalyses the carbonylation of methanol with initial rates up to 44 mol dm-3 h-1 before decaying to a second catalytic phase with rates of 3 mol dm-3 h-1; [CoI(CO)2(PEt3)2], which is trigonal bipyramidal with axial PEt3 ligands, has been isolated from the final reaction solution.

AB - [Cp(*)Co(CO)2] in the presence of PEt3 and Mel catalyses the carbonylation of methanol with initial rates up to 44 mol dm-3 h-1 before decaying to a second catalytic phase with rates of 3 mol dm-3 h-1; [CoI(CO)2(PEt3)2], which is trigonal bipyramidal with axial PEt3 ligands, has been isolated from the final reaction solution.

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U2 - 10.1039/a903169c

DO - 10.1039/a903169c

M3 - Article

AN - SCOPUS:0033533169

SN - 1359-7345

SP - 1379

EP - 1380

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

High activity cobalt based catalysts for the carbonylation of methanol

Abstract

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