Heteronuclear bimetallic complexes with 3d and 4f elements

Brian A. Chalmers; David B. Cordes; Lauren Bertram; Daniel J. Harraghy; Rachel C. Reid; Iain A. Smellie; Anna E. Tarcza; Brodie J. Thomson

doi:10.3390/M1577

Heteronuclear bimetallic complexes with 3d and 4f elements

Brian A. Chalmers^*, David B. Cordes, Lauren Bertram, Daniel J. Harraghy, Rachel C. Reid, Iain A. Smellie, Anna E. Tarcza, Brodie J. Thomson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Three heteronuclear bimetallic complexes [Cu(MeOH)(L)Ln(NO3)3] (1-Ce; Ln = Ce, 1-Pr; Ln = Pr, and 1-Nd; Ln = Nd) were prepared using H₂L (1,3-bis[(3-methoxysalicylidene)amino]-2,2-dimethylpropane) in methanol, affording the complexes as green crystalline materials. These can be prepared in a one-pot synthesis from 2,2-dimethylpropan-1,3-diamine, o-vanillin, copper(II) nitrate, and Ln(III) nitrate (Ln = Ce, Pr, Nd). X-ray crystallography, high-resolution mass spectrometry, and UV-vis spectroscopy were used to characterize the bimetallic complexes. All three complexes showed the copper center adopting a five-coordinate square pyramidal geometry and the lanthanoid cation adopting a ten-coordinate geometry.

Original language	English
Article number	M1577
Number of pages	9
Journal	Molbank
Volume	2023
Issue number	1
DOIs	https://doi.org/10.3390/M1577
Publication status	Published - 3 Feb 2023

Keywords

X-ray crystallography
Bimetallic complexes
UV-vis spectroscopy
HRMS spectrometry

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10.3390/M1577Licence: CC BY

Chalmers-2023-Heteronuclear-bimeticallic-Molbank-2023-M1577-CCBY
Copyright: © 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/4.0/).
Final published version, 1.59 MBLicence: CC BY

CCDC 2224393 - 2224395: Experimental Crystal Structure Determination
Chalmers, B. A. (Creator), Cordes, D. B. (Creator), Bertram, L. (Creator), Harraghy, D. J. (Creator), Reid, R. C. (Creator), Smellie, I. A. (Creator), Tarcza, A. E. (Creator) & Thomson, B. J. (Creator), Cambridge Crystallographic Data Centre, 2023
DOI: 10.5517/ccdc.csd.cc2dnnmc, https://dx.doi.org/10.5517/ccdc.csd.cc2dnnnd and one more link, https://dx.doi.org/10.5517/ccdc.csd.cc2dnnpf (show fewer)
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title = "Heteronuclear bimetallic complexes with 3d and 4f elements",

abstract = "Three heteronuclear bimetallic complexes [Cu(MeOH)(L)Ln(NO3)3] (1-Ce; Ln = Ce, 1-Pr; Ln = Pr, and 1-Nd; Ln = Nd) were prepared using H2L (1,3-bis[(3-methoxysalicylidene)amino]-2,2-dimethylpropane) in methanol, affording the complexes as green crystalline materials. These can be prepared in a one-pot synthesis from 2,2-dimethylpropan-1,3-diamine, o-vanillin, copper(II) nitrate, and Ln(III) nitrate (Ln = Ce, Pr, Nd). X-ray crystallography, high-resolution mass spectrometry, and UV-vis spectroscopy were used to characterize the bimetallic complexes. All three complexes showed the copper center adopting a five-coordinate square pyramidal geometry and the lanthanoid cation adopting a ten-coordinate geometry.",

keywords = "X-ray crystallography, Bimetallic complexes, UV-vis spectroscopy, HRMS spectrometry",

author = "Chalmers, {Brian A.} and Cordes, {David B.} and Lauren Bertram and Harraghy, {Daniel J.} and Reid, {Rachel C.} and Smellie, {Iain A.} and Tarcza, {Anna E.} and Thomson, {Brodie J.}",

year = "2023",

month = feb,

day = "3",

doi = "10.3390/M1577",

language = "English",

volume = "2023",

journal = "Molbank",

issn = "1422-8599",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

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TY - JOUR

T1 - Heteronuclear bimetallic complexes with 3d and 4f elements

AU - Chalmers, Brian A.

AU - Cordes, David B.

AU - Bertram, Lauren

AU - Harraghy, Daniel J.

AU - Reid, Rachel C.

AU - Smellie, Iain A.

AU - Tarcza, Anna E.

AU - Thomson, Brodie J.

PY - 2023/2/3

Y1 - 2023/2/3

N2 - Three heteronuclear bimetallic complexes [Cu(MeOH)(L)Ln(NO3)3] (1-Ce; Ln = Ce, 1-Pr; Ln = Pr, and 1-Nd; Ln = Nd) were prepared using H2L (1,3-bis[(3-methoxysalicylidene)amino]-2,2-dimethylpropane) in methanol, affording the complexes as green crystalline materials. These can be prepared in a one-pot synthesis from 2,2-dimethylpropan-1,3-diamine, o-vanillin, copper(II) nitrate, and Ln(III) nitrate (Ln = Ce, Pr, Nd). X-ray crystallography, high-resolution mass spectrometry, and UV-vis spectroscopy were used to characterize the bimetallic complexes. All three complexes showed the copper center adopting a five-coordinate square pyramidal geometry and the lanthanoid cation adopting a ten-coordinate geometry.

AB - Three heteronuclear bimetallic complexes [Cu(MeOH)(L)Ln(NO3)3] (1-Ce; Ln = Ce, 1-Pr; Ln = Pr, and 1-Nd; Ln = Nd) were prepared using H2L (1,3-bis[(3-methoxysalicylidene)amino]-2,2-dimethylpropane) in methanol, affording the complexes as green crystalline materials. These can be prepared in a one-pot synthesis from 2,2-dimethylpropan-1,3-diamine, o-vanillin, copper(II) nitrate, and Ln(III) nitrate (Ln = Ce, Pr, Nd). X-ray crystallography, high-resolution mass spectrometry, and UV-vis spectroscopy were used to characterize the bimetallic complexes. All three complexes showed the copper center adopting a five-coordinate square pyramidal geometry and the lanthanoid cation adopting a ten-coordinate geometry.

KW - X-ray crystallography

KW - Bimetallic complexes

KW - UV-vis spectroscopy

KW - HRMS spectrometry

U2 - 10.3390/M1577

DO - 10.3390/M1577

M3 - Article

SN - 1422-8599

VL - 2023

JO - Molbank

JF - Molbank

IS - 1

M1 - M1577

ER -

Heteronuclear bimetallic complexes with 3d and 4f elements

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Datasets

CCDC 2224393 - 2224395: Experimental Crystal Structure Determination

Cite this