Halide exchanged Hoveyda-type complexes in olefin metathesis

Julia Wappel; Cesar A. Urbina-Blanco; Mudassar Abbas; Joerg H. Albering; Robert Saf; Steven P. Nolan; Christian Slugovc

doi:10.3762/bjoc.6.125

Halide exchanged Hoveyda-type complexes in olefin metathesis

Julia Wappel, Cesar A. Urbina-Blanco, Mudassar Abbas, Joerg H. Albering, Robert Saf, Steven P. Nolan, Christian Slugovc

Research output: Contribution to journal › Article › peer-review

Abstract

The aims of this contribution are to present a straightforward synthesis of 2(nd) generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic performance of the complexes in ring opening metathesis polymerisation, ring closing metathesis, enyne cycloisomerisation and cross metathesis reactions.

Original language	English
Pages (from-to)	1091-1098
Number of pages	8
Journal	Beilstein Journal of Organic Chemistry
Volume	6
DOIs	https://doi.org/10.3762/bjoc.6.125
Publication status	Published - Nov 2010

Keywords

Cross metathesis
Olefin metathesis
RCM
ROMP
Ruthenium

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10.3762/bjoc.6.125

6-125
© 2010 Wappel et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)
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Cite this

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title = "Halide exchanged Hoveyda-type complexes in olefin metathesis",

abstract = "The aims of this contribution are to present a straightforward synthesis of 2(nd) generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic performance of the complexes in ring opening metathesis polymerisation, ring closing metathesis, enyne cycloisomerisation and cross metathesis reactions.",

keywords = "Cross metathesis, Olefin metathesis, RCM, ROMP, Ruthenium",

author = "Julia Wappel and Urbina-Blanco, {Cesar A.} and Mudassar Abbas and Albering, {Joerg H.} and Robert Saf and Nolan, {Steven P.} and Christian Slugovc",

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doi = "10.3762/bjoc.6.125",

language = "English",

volume = "6",

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T1 - Halide exchanged Hoveyda-type complexes in olefin metathesis

AU - Wappel, Julia

AU - Urbina-Blanco, Cesar A.

AU - Abbas, Mudassar

AU - Albering, Joerg H.

AU - Saf, Robert

AU - Nolan, Steven P.

AU - Slugovc, Christian

PY - 2010/11

Y1 - 2010/11

N2 - The aims of this contribution are to present a straightforward synthesis of 2(nd) generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic performance of the complexes in ring opening metathesis polymerisation, ring closing metathesis, enyne cycloisomerisation and cross metathesis reactions.

AB - The aims of this contribution are to present a straightforward synthesis of 2(nd) generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic performance of the complexes in ring opening metathesis polymerisation, ring closing metathesis, enyne cycloisomerisation and cross metathesis reactions.

KW - Cross metathesis

KW - Olefin metathesis

KW - RCM

KW - ROMP

KW - Ruthenium

U2 - 10.3762/bjoc.6.125

DO - 10.3762/bjoc.6.125

M3 - Article

VL - 6

SP - 1091

EP - 1098

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

ER -

Halide exchanged Hoveyda-type complexes in olefin metathesis

Abstract

Keywords

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