Halide exchanged Hoveyda-type complexes in olefin metathesis

Julia Wappel, Cesar A. Urbina-Blanco, Mudassar Abbas, Joerg H. Albering, Robert Saf, Steven P. Nolan, Christian Slugovc

Research output: Contribution to journalArticlepeer-review

43 Citations (Scopus)

Abstract

The aims of this contribution are to present a straightforward synthesis of 2(nd) generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic performance of the complexes in ring opening metathesis polymerisation, ring closing metathesis, enyne cycloisomerisation and cross metathesis reactions.

Original languageEnglish
Pages (from-to)1091-1098
Number of pages8
JournalBeilstein Journal of Organic Chemistry
Volume6
DOIs
Publication statusPublished - Nov 2010

Keywords

  • Cross metathesis
  • Olefin metathesis
  • RCM
  • ROMP
  • Ruthenium

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