Half-rotation in a [2] catenane via interconvertible Pd(II) coordination modes

D A  Leigh; P J  Lusby; A M Z  Slawin; D B  Walker

doi:10.1039/b510663j

Half-rotation in a [2] catenane via interconvertible Pd(II) coordination modes

D A Leigh, P J Lusby, A M Z Slawin, D B Walker

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of a [2] catenane with Pd(OAc)(2) binds both macrocycles to the metal, locking them in position; treatment with PdCl2, however, results in coordination of only one ring, producing a half-turn in the relative orientation of the [2] catenane components in both solution and the solid state.

Original language	English
Pages (from-to)	4919-4921
Number of pages	3
Journal	Chemical Communications
Issue number	39
DOIs	https://doi.org/10.1039/b510663j
Publication status	Published - 2005

Keywords

COMPLEXATION
MOTIONS
SWITCH

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10.1039/b510663j

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title = "Half-rotation in a [2] catenane via interconvertible Pd(II) coordination modes",

abstract = "Reaction of a [2] catenane with Pd(OAc)(2) binds both macrocycles to the metal, locking them in position; treatment with PdCl2, however, results in coordination of only one ring, producing a half-turn in the relative orientation of the [2] catenane components in both solution and the solid state.",

keywords = "COMPLEXATION, MOTIONS, SWITCH",

author = "Leigh, {D A} and Lusby, {P J} and Slawin, {A M Z} and Walker, {D B}",

year = "2005",

doi = "10.1039/b510663j",

language = "English",

pages = "4919--4921",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "39",

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T1 - Half-rotation in a [2] catenane via interconvertible Pd(II) coordination modes

AU - Leigh, D A

AU - Lusby, P J

AU - Slawin, A M Z

AU - Walker, D B

PY - 2005

Y1 - 2005

N2 - Reaction of a [2] catenane with Pd(OAc)(2) binds both macrocycles to the metal, locking them in position; treatment with PdCl2, however, results in coordination of only one ring, producing a half-turn in the relative orientation of the [2] catenane components in both solution and the solid state.

AB - Reaction of a [2] catenane with Pd(OAc)(2) binds both macrocycles to the metal, locking them in position; treatment with PdCl2, however, results in coordination of only one ring, producing a half-turn in the relative orientation of the [2] catenane components in both solution and the solid state.

KW - COMPLEXATION

KW - MOTIONS

KW - SWITCH

UR - http://www.scopus.com/inward/record.url?scp=27444444604&partnerID=8YFLogxK

U2 - 10.1039/b510663j

DO - 10.1039/b510663j

M3 - Article

SN - 1359-7345

SP - 4919

EP - 4921

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

Half-rotation in a [2] catenane via interconvertible Pd(II) coordination modes

Abstract

Keywords

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