Abstract
Furans and pyrroles were prepared via the gold(I)-catalyzed
alkyne hydration of diynes. The use of [Au(IPr)OH] as
precatalyst in a silver-free protocol permits low catalyst loadings
and in situ generation of the active cationic gold species. A
detailed computational study confirmed the experimental results
and supports the proposed mechanism
alkyne hydration of diynes. The use of [Au(IPr)OH] as
precatalyst in a silver-free protocol permits low catalyst loadings
and in situ generation of the active cationic gold species. A
detailed computational study confirmed the experimental results
and supports the proposed mechanism
| Original language | English |
|---|---|
| Pages (from-to) | 58-61 |
| Number of pages | 4 |
| Journal | Catalysis Science and Technology |
| Volume | 1 |
| Early online date | 31 Jan 2011 |
| DOIs | |
| Publication status | Published - 2011 |
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