Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration

Pierrick Nun; Stephanie Dupuy; Sylvain Gaillard; Albert Poater; Luigi Cavallo; Steven Patrick Nolan

doi:10.1039/C0CY00055H

Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration

Pierrick Nun, Stephanie Dupuy, Sylvain Gaillard, Albert Poater, Luigi Cavallo, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

Furans and pyrroles were prepared via the gold(I)-catalyzed
alkyne hydration of diynes. The use of [Au(IPr)OH] as
precatalyst in a silver-free protocol permits low catalyst loadings
and in situ generation of the active cationic gold species. A
detailed computational study confirmed the experimental results
and supports the proposed mechanism

Original language	English
Pages (from-to)	58-61
Number of pages	4
Journal	Catalysis Science and Technology
Volume	1
Early online date	31 Jan 2011
DOIs	https://doi.org/10.1039/C0CY00055H
Publication status	Published - 2011

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@article{05571f306bbe4200b9b21404299efab0,

title = "Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration",

abstract = "Furans and pyrroles were prepared via the gold(I)-catalyzedalkyne hydration of diynes. The use of [Au(IPr)OH] asprecatalyst in a silver-free protocol permits low catalyst loadingsand in situ generation of the active cationic gold species. Adetailed computational study confirmed the experimental resultsand supports the proposed mechanism",

author = "Pierrick Nun and Stephanie Dupuy and Sylvain Gaillard and Albert Poater and Luigi Cavallo and Nolan, {Steven Patrick}",

year = "2011",

doi = "10.1039/C0CY00055H",

language = "English",

volume = "1",

pages = "58--61",

journal = "Catalysis Science and Technology",

issn = "2044-4761",

publisher = "Royal Society of Chemistry",

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T1 - Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration

AU - Nun, Pierrick

AU - Dupuy, Stephanie

AU - Gaillard, Sylvain

AU - Poater, Albert

AU - Cavallo, Luigi

AU - Nolan, Steven Patrick

PY - 2011

Y1 - 2011

N2 - Furans and pyrroles were prepared via the gold(I)-catalyzedalkyne hydration of diynes. The use of [Au(IPr)OH] asprecatalyst in a silver-free protocol permits low catalyst loadingsand in situ generation of the active cationic gold species. Adetailed computational study confirmed the experimental resultsand supports the proposed mechanism

AB - Furans and pyrroles were prepared via the gold(I)-catalyzedalkyne hydration of diynes. The use of [Au(IPr)OH] asprecatalyst in a silver-free protocol permits low catalyst loadingsand in situ generation of the active cationic gold species. Adetailed computational study confirmed the experimental resultsand supports the proposed mechanism

U2 - 10.1039/C0CY00055H

DO - 10.1039/C0CY00055H

M3 - Article

SN - 2044-4761

VL - 1

SP - 58

EP - 61

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

ER -

Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration

Abstract

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