Abstract
We have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer-Schuster rearrangement. They proved to be highly efficient in both reactions.
| Original language | English |
|---|---|
| Pages (from-to) | 117-120 |
| Number of pages | 4 |
| Journal | ChemCatChem |
| Volume | 9 |
| Issue number | 1 |
| Early online date | 14 Dec 2016 |
| DOIs | |
| Publication status | Published - 12 Jan 2017 |
Keywords
- MEYER-SCHUSTER REARRANGEMENT
- ONE-POT SYNTHESIS
- MECHANISTIC INSIGHTS
- SILVER-FREE
- CATALYSIS
- ALKYNES
- COUNTERION
- HYDRATION
- REACTIVITY
- ALCOHOLS
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Gold-N-Heterocyclic Carbene Complexes of Mineral Acids (dataset)
Brill, M. (Creator), Nahra, F. (Creator), Gomez Herrera, A. (Creator), Zinser, C. M. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator) & Nolan, S. P. (Creator), Cambridge Crystallographic Data Centre, 22 Sept 2016
https://dx.doi.org/10.5517/ccdc.csd.cc1mjzlq and 2 more links, https://dx.doi.org/10.5517/ccdc.csd.cc1mjzmr, https://dx.doi.org/10.5517/ccdc.csd.cc1mjzns (show fewer)
Dataset