Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5-dienes: a new tin-free homolytic route to beta- and gamma-lactams

L V  Jackson; John Christopher Walton

doi:10.1039/B007454N

Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5-dienes: a new tin-free homolytic route to beta- and gamma-lactams

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Abstract

Radical induced homolyses of 1-carbamoyl-1-methylcyclohexa-2,5-dienes took place cleanly to yield aminoacyl radicals, with no competition from the alternative dissociation to methyl radicals: beta- and gamma -lactams were obtained from ring closures of suitably unsaturated model compounds.

Original language	English
Pages (from-to)	2327-2328
Number of pages	2
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/B007454N
Publication status	Published - 2000

Keywords

CYCLOHEXA-1,4-DIENE-3-CARBOXYLATES
2,5-DIHYDROFURAN-2-CARBOXYLATES

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10.1039/B007454N

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title = "Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5-dienes: a new tin-free homolytic route to beta- and gamma-lactams",

abstract = "Radical induced homolyses of 1-carbamoyl-1-methylcyclohexa-2,5-dienes took place cleanly to yield aminoacyl radicals, with no competition from the alternative dissociation to methyl radicals: beta- and gamma -lactams were obtained from ring closures of suitably unsaturated model compounds.",

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author = "Jackson, {L V} and Walton, {John Christopher}",

year = "2000",

doi = "10.1039/B007454N",

language = "English",

pages = "2327--2328",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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AU - Walton, John Christopher

PY - 2000

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AB - Radical induced homolyses of 1-carbamoyl-1-methylcyclohexa-2,5-dienes took place cleanly to yield aminoacyl radicals, with no competition from the alternative dissociation to methyl radicals: beta- and gamma -lactams were obtained from ring closures of suitably unsaturated model compounds.

KW - CYCLOHEXA-1,4-DIENE-3-CARBOXYLATES

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ER -

Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5-dienes: a new tin-free homolytic route to beta- and gamma-lactams

Abstract

Keywords

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