Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5-dienes: a new tin-free homolytic route to beta- and gamma-lactams

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Abstract

Radical induced homolyses of 1-carbamoyl-1-methylcyclohexa-2,5-dienes took place cleanly to yield aminoacyl radicals, with no competition from the alternative dissociation to methyl radicals: beta- and gamma -lactams were obtained from ring closures of suitably unsaturated model compounds.

Original languageEnglish
Pages (from-to)2327-2328
Number of pages2
JournalChemical Communications
Issue number23
DOIs
Publication statusPublished - 2000

Keywords

  • CYCLOHEXA-1,4-DIENE-3-CARBOXYLATES
  • 2,5-DIHYDROFURAN-2-CARBOXYLATES

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