Further investigations into the isomerism of Cu(II) complexes of diphenylsulfimide: the preparation and X-ray crystal structure of {[Cu(Ph2SNH)4][CuBr2(Ph2SNH)2]Br2, the first example of a {[CuL4][CuX2L2]X2

PF Kelly; Alexandra Martha Zoya Slawin; KW Waring; S Wilson

Further investigations into the isomerism of Cu(II) complexes of diphenylsulfimide: the preparation and X-ray crystal structure of {[Cu(Ph₂SNH)₄][CuBr₂(Ph₂SNH)₂]Br₂, the first example of a {[CuL₄][CuX₂L₂]X₂

PF Kelly, Alexandra Martha Zoya Slawin, KW Waring, S Wilson

Research output: Contribution to journal › Article › peer-review

Abstract

Green crystalline [Cu(Ph2SNH)(4)][CuBr2(Ph2SNH)(2)]Br-2 (2) forms when the product of the reaction of CuBr2 with Ph2SNH (1) (molar ratio 1:3) in MeCN is extracted into CH2Cl2-60/80 petroleum ether and the solvents allowed to evaporate slowly. The product is notable for two reasons: not only does it contain the CuBr2(Ph2SNH)(2) unit in the hitherto unseen planar isomer (the free material forming only the pseudo-tetrahedral isomer), but, more significantly, it is also the first example of a structurally characterised [CuL4][CuX2L2]X-2 system. (C) 2001 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	201-204
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	312
Publication status	Published - 29 Jan 2001

Keywords

isomerism
copper(II) complexes
crystal structures
sulfimides

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@article{eeabf72142ee4f0e9b2e4b787e9b96a2,

title = "Further investigations into the isomerism of Cu(II) complexes of diphenylsulfimide: the preparation and X-ray crystal structure of {[Cu(Ph2SNH)4][CuBr2(Ph2SNH)2]Br2, the first example of a {[CuL4][CuX2L2]X2",

abstract = "Green crystalline [Cu(Ph2SNH)(4)][CuBr2(Ph2SNH)(2)]Br-2 (2) forms when the product of the reaction of CuBr2 with Ph2SNH (1) (molar ratio 1:3) in MeCN is extracted into CH2Cl2-60/80 petroleum ether and the solvents allowed to evaporate slowly. The product is notable for two reasons: not only does it contain the CuBr2(Ph2SNH)(2) unit in the hitherto unseen planar isomer (the free material forming only the pseudo-tetrahedral isomer), but, more significantly, it is also the first example of a structurally characterised [CuL4][CuX2L2]X-2 system. (C) 2001 Elsevier Science B.V. All rights reserved.",

keywords = "isomerism, copper(II) complexes, crystal structures, sulfimides",

author = "PF Kelly and Slawin, {Alexandra Martha Zoya} and KW Waring and S Wilson",

year = "2001",

month = jan,

day = "29",

language = "English",

volume = "312",

pages = "201--204",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

Further investigations into the isomerism of Cu(II) complexes of diphenylsulfimide: the preparation and X-ray crystal structure of {[Cu(Ph₂SNH)₄][CuBr₂(Ph₂SNH)₂]Br₂, the first example of a {[CuL₄][CuX₂L₂]X₂. / Kelly, PF; Slawin, Alexandra Martha Zoya; Waring, KW et al.
In: Inorganica Chimica Acta, Vol. 312, 29.01.2001, p. 201-204.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Further investigations into the isomerism of Cu(II) complexes of diphenylsulfimide: the preparation and X-ray crystal structure of {[Cu(Ph2SNH)4][CuBr2(Ph2SNH)2]Br2, the first example of a {[CuL4][CuX2L2]X2

AU - Kelly, PF

AU - Slawin, Alexandra Martha Zoya

AU - Waring, KW

AU - Wilson, S

PY - 2001/1/29

Y1 - 2001/1/29

N2 - Green crystalline [Cu(Ph2SNH)(4)][CuBr2(Ph2SNH)(2)]Br-2 (2) forms when the product of the reaction of CuBr2 with Ph2SNH (1) (molar ratio 1:3) in MeCN is extracted into CH2Cl2-60/80 petroleum ether and the solvents allowed to evaporate slowly. The product is notable for two reasons: not only does it contain the CuBr2(Ph2SNH)(2) unit in the hitherto unseen planar isomer (the free material forming only the pseudo-tetrahedral isomer), but, more significantly, it is also the first example of a structurally characterised [CuL4][CuX2L2]X-2 system. (C) 2001 Elsevier Science B.V. All rights reserved.

AB - Green crystalline [Cu(Ph2SNH)(4)][CuBr2(Ph2SNH)(2)]Br-2 (2) forms when the product of the reaction of CuBr2 with Ph2SNH (1) (molar ratio 1:3) in MeCN is extracted into CH2Cl2-60/80 petroleum ether and the solvents allowed to evaporate slowly. The product is notable for two reasons: not only does it contain the CuBr2(Ph2SNH)(2) unit in the hitherto unseen planar isomer (the free material forming only the pseudo-tetrahedral isomer), but, more significantly, it is also the first example of a structurally characterised [CuL4][CuX2L2]X-2 system. (C) 2001 Elsevier Science B.V. All rights reserved.

KW - isomerism

KW - copper(II) complexes

KW - crystal structures

KW - sulfimides

UR - http://www.scopus.com/inward/record.url?scp=0035966468&partnerID=8YFLogxK

M3 - Article

SN - 0020-1693

VL - 312

SP - 201

EP - 204

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta