From ruthenium olefin metathesis catalyst to (ŋ5 -3-phenylindenyl)hydrido complex via alcoholysis

Simone Manzini; David J. Nelson; Tomas Lebl; Albert Poater; Luigi Cavallo; Alexandra M. Z. Slawin; Steven P. Nolan

doi:10.1039/c3cc49481k

From ruthenium olefin metathesis catalyst to (ŋ⁵ -3-phenylindenyl)hydrido complex via alcoholysis

Simone Manzini, David J. Nelson, Tomas Lebl, Albert Poater, Luigi Cavallo, Alexandra M. Z. Slawin, Steven P. Nolan^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterisation of [Ru(H)(η⁵-3-phenylindenyl)(ⁱBu-Phoban)₂] 4 is reported (ⁱBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst _11M, in a process that was previously thought to be limited to analogous complex [RuCl₂(PPh₃)₂(3-phenylindenylidene)] (_10M).

Original language	English
Pages (from-to)	2205-2207
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	17
Early online date	10 Jan 2014
DOIs	https://doi.org/10.1039/c3cc49481k
Publication status	Published - 2014

Keywords

Indenylidene Complexes
Phenylindenyl Complex
Grubbs Catalysts
Isomerization

Access to Document

10.1039/c3cc49481k

Wolfson Research Merit Award: Wolfson Research Merit Award
Nolan, S. P. (PI)
The Royal Society
1/08/10 → 31/07/15
Project: Standard
FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis
Nolan, S. P. (PI)
European Research Council
1/01/09 → 31/12/14
Project: Standard
EUMET: EU FP7 'EUMET' Olefin Metathesis as a Practical Synthetic Tool
Nolan, S. P. (PI)
European Commission
1/11/08 → 31/10/12
Project: Standard

Cite this

@article{bcddf1179c1c455691d997172b028757,

title = "From ruthenium olefin metathesis catalyst to ({\ng}5 -3-phenylindenyl)hydrido complex via alcoholysis",

abstract = "The synthesis and characterisation of [Ru(H)(η5-3-phenylindenyl)(iBu-Phoban)2] 4 is reported (iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst 11M, in a process that was previously thought to be limited to analogous complex [RuCl2(PPh3)2(3-phenylindenylidene)] (10M).",

keywords = "Indenylidene Complexes, Phenylindenyl Complex, Grubbs Catalysts, Isomerization",

author = "Simone Manzini and Nelson, {David J.} and Tomas Lebl and Albert Poater and Luigi Cavallo and Slawin, {Alexandra M. Z.} and Nolan, {Steven P.}",

year = "2014",

doi = "10.1039/c3cc49481k",

language = "English",

volume = "50",

pages = "2205--2207",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

}

TY - JOUR

T1 - From ruthenium olefin metathesis catalyst to (ŋ5 -3-phenylindenyl)hydrido complex via alcoholysis

AU - Manzini, Simone

AU - Nelson, David J.

AU - Lebl, Tomas

AU - Poater, Albert

AU - Cavallo, Luigi

AU - Slawin, Alexandra M. Z.

AU - Nolan, Steven P.

PY - 2014

Y1 - 2014

N2 - The synthesis and characterisation of [Ru(H)(η5-3-phenylindenyl)(iBu-Phoban)2] 4 is reported (iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst 11M, in a process that was previously thought to be limited to analogous complex [RuCl2(PPh3)2(3-phenylindenylidene)] (10M).

AB - The synthesis and characterisation of [Ru(H)(η5-3-phenylindenyl)(iBu-Phoban)2] 4 is reported (iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst 11M, in a process that was previously thought to be limited to analogous complex [RuCl2(PPh3)2(3-phenylindenylidene)] (10M).

KW - Indenylidene Complexes

KW - Phenylindenyl Complex

KW - Grubbs Catalysts

KW - Isomerization

U2 - 10.1039/c3cc49481k

DO - 10.1039/c3cc49481k

M3 - Article

SN - 1359-7345

VL - 50

SP - 2205

EP - 2207

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

From ruthenium olefin metathesis catalyst to (ŋ5 -3-phenylindenyl)hydrido complex via alcoholysis

Abstract

Keywords

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Projects

Wolfson Research Merit Award: Wolfson Research Merit Award

FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis

EUMET: EU FP7 'EUMET' Olefin Metathesis as a Practical Synthetic Tool

Cite this

From ruthenium olefin metathesis catalyst to (ŋ⁵ -3-phenylindenyl)hydrido complex via alcoholysis