Free radical addition to olefins. Part 23. Kinetics of the addition of chloroiodomethane to ethylene and vinyl fluoride

Ian Paterson; John M. Tedder; John C. Walton

Free radical addition to olefins. Part 23. Kinetics of the addition of chloroiodomethane to ethylene and vinyl fluoride

Ian Paterson, John M. Tedder, John C. Walton^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The gas phase reaction of CH₂ClI with ethylene and vinyl fluoride, initiated photochemically and thermally with di-t-butyl peroxide, has been investigated, and the relative rates of addition of chloromethyl radicals to both ends of vinyl fluoride have been determined over a range of temperatures. The mechanism of the reaction is discussed, and the relative Arrhenius parameters for addition to the two alkenes are interpreted in terms of frontier orbital coefficients.

Original language	English
Pages (from-to)	884-887
Number of pages	4
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	9
Publication status	Published - 1 Dec 1978

Cite this

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title = "Free radical addition to olefins. Part 23. Kinetics of the addition of chloroiodomethane to ethylene and vinyl fluoride",

abstract = "The gas phase reaction of CH2ClI with ethylene and vinyl fluoride, initiated photochemically and thermally with di-t-butyl peroxide, has been investigated, and the relative rates of addition of chloromethyl radicals to both ends of vinyl fluoride have been determined over a range of temperatures. The mechanism of the reaction is discussed, and the relative Arrhenius parameters for addition to the two alkenes are interpreted in terms of frontier orbital coefficients.",

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AU - Walton, John C.

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N2 - The gas phase reaction of CH2ClI with ethylene and vinyl fluoride, initiated photochemically and thermally with di-t-butyl peroxide, has been investigated, and the relative rates of addition of chloromethyl radicals to both ends of vinyl fluoride have been determined over a range of temperatures. The mechanism of the reaction is discussed, and the relative Arrhenius parameters for addition to the two alkenes are interpreted in terms of frontier orbital coefficients.

AB - The gas phase reaction of CH2ClI with ethylene and vinyl fluoride, initiated photochemically and thermally with di-t-butyl peroxide, has been investigated, and the relative rates of addition of chloromethyl radicals to both ends of vinyl fluoride have been determined over a range of temperatures. The mechanism of the reaction is discussed, and the relative Arrhenius parameters for addition to the two alkenes are interpreted in terms of frontier orbital coefficients.

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IS - 9

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Free radical addition to olefins. Part 23. Kinetics of the addition of chloroiodomethane to ethylene and vinyl fluoride

Abstract

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