Fraternal twin iridium hemicage chelates

Gabriel St-Pierre; Sebastien Ladouceur; Daniel Fortin; Eli Zysman-Colman

doi:10.1039/C1DT11236H

Fraternal twin iridium hemicage chelates

Gabriel St-Pierre, Sebastien Ladouceur, Daniel Fortin, Eli Zysman-Colman

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and complete photophysical characterization of rigidified neutral hemicage iridium complexes are presented. The hemicage ligands were obtained via a modular synthesis, which will facilitate the expansion of future hemicage syntheses. Slight variations in structure between the two iridium hemicage podates reveal subtle differences in photophysical behavior, which will aid in the design of functional materials. A parallel computational investigation corroborates the experimental findings. The insight gleaned from this study will have an impact for the design of iridium-based luminophores for OLED-type applications.

Original language	Undefined/Unknown
Pages (from-to)	11726-11731
Number of pages	6
Journal	Dalton Transactions
Volume	40
Issue number	44
DOIs	https://doi.org/10.1039/C1DT11236H
Publication status	Published - 2011

Access to Document

10.1039/C1DT11236H

Cite this

@article{bdf8ab7b5ee34312898f097375437d3e,

title = "Fraternal twin iridium hemicage chelates",

abstract = "The synthesis and complete photophysical characterization of rigidified neutral hemicage iridium complexes are presented. The hemicage ligands were obtained via a modular synthesis, which will facilitate the expansion of future hemicage syntheses. Slight variations in structure between the two iridium hemicage podates reveal subtle differences in photophysical behavior, which will aid in the design of functional materials. A parallel computational investigation corroborates the experimental findings. The insight gleaned from this study will have an impact for the design of iridium-based luminophores for OLED-type applications.",

author = "Gabriel St-Pierre and Sebastien Ladouceur and Daniel Fortin and Eli Zysman-Colman",

year = "2011",

doi = "10.1039/C1DT11236H",

language = "Undefined/Unknown",

volume = "40",

pages = "11726--11731",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "44",

}

TY - JOUR

T1 - Fraternal twin iridium hemicage chelates

AU - St-Pierre, Gabriel

AU - Ladouceur, Sebastien

AU - Fortin, Daniel

AU - Zysman-Colman, Eli

PY - 2011

Y1 - 2011

N2 - The synthesis and complete photophysical characterization of rigidified neutral hemicage iridium complexes are presented. The hemicage ligands were obtained via a modular synthesis, which will facilitate the expansion of future hemicage syntheses. Slight variations in structure between the two iridium hemicage podates reveal subtle differences in photophysical behavior, which will aid in the design of functional materials. A parallel computational investigation corroborates the experimental findings. The insight gleaned from this study will have an impact for the design of iridium-based luminophores for OLED-type applications.

AB - The synthesis and complete photophysical characterization of rigidified neutral hemicage iridium complexes are presented. The hemicage ligands were obtained via a modular synthesis, which will facilitate the expansion of future hemicage syntheses. Slight variations in structure between the two iridium hemicage podates reveal subtle differences in photophysical behavior, which will aid in the design of functional materials. A parallel computational investigation corroborates the experimental findings. The insight gleaned from this study will have an impact for the design of iridium-based luminophores for OLED-type applications.

UR - http://dx.doi.org/10.1039/C1DT11236H

U2 - 10.1039/C1DT11236H

DO - 10.1039/C1DT11236H

M3 - Article

SN - 1477-9226

VL - 40

SP - 11726

EP - 11731

JO - Dalton Transactions

JF - Dalton Transactions

IS - 44

ER -

Fraternal twin iridium hemicage chelates

Abstract

Access to Document

Other files and links

Cite this