Formation of the bidentate [Ph2SNC(Me)N(H)] ligand by metal-assisted sulfimide addition to acetonitrile; X-ray crystal structure of [Pt(Ph2SNH)(Ph2SNC(Me)NH)Cl]Cl.MeCN

Alexandra Martha Zoya Slawin; PF Kelly

Formation of the bidentate [Ph₂SNC(Me)N(H)] ligand by metal-assisted sulfimide addition to acetonitrile; X-ray crystal structure of [Pt(Ph₂SNH)(Ph₂SNC(Me)NH)Cl]Cl.MeCN

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Abstract

In contrast to similar reactions of Cu, Co and Pd species, the platinum(II) complex [Pt(MeCN)(2)Cl-2] reacts with Ph2SNH (ratio 1:2) in MeCN via a metal assisted addition of the sulfimide to the acetonitrile to give [Pt(Ph2SNH)(Ph2SNC(Me)NH)CI]Cl . MeCN, the first example of a complex of the bidentate [Ph2SNC(Me)N(H)] ligand.

Original language	English
Pages (from-to)	1081-1082
Number of pages	2
Journal	Chemical Communications
Publication status	Published - 21 Jun 1999

Keywords

COMPLEXES
PALLADIUM

Cite this

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title = "Formation of the bidentate [Ph2SNC(Me)N(H)] ligand by metal-assisted sulfimide addition to acetonitrile; X-ray crystal structure of [Pt(Ph2SNH)(Ph2SNC(Me)NH)Cl]Cl.MeCN",

abstract = "In contrast to similar reactions of Cu, Co and Pd species, the platinum(II) complex [Pt(MeCN)(2)Cl-2] reacts with Ph2SNH (ratio 1:2) in MeCN via a metal assisted addition of the sulfimide to the acetonitrile to give [Pt(Ph2SNH)(Ph2SNC(Me)NH)CI]Cl . MeCN, the first example of a complex of the bidentate [Ph2SNC(Me)N(H)] ligand.",

keywords = "COMPLEXES, PALLADIUM",

author = "Slawin, {Alexandra Martha Zoya} and PF Kelly",

year = "1999",

month = jun,

day = "21",

language = "English",

pages = "1081--1082",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Formation of the bidentate [Ph2SNC(Me)N(H)] ligand by metal-assisted sulfimide addition to acetonitrile; X-ray crystal structure of [Pt(Ph2SNH)(Ph2SNC(Me)NH)Cl]Cl.MeCN

AU - Slawin, Alexandra Martha Zoya

AU - Kelly, PF

PY - 1999/6/21

Y1 - 1999/6/21

N2 - In contrast to similar reactions of Cu, Co and Pd species, the platinum(II) complex [Pt(MeCN)(2)Cl-2] reacts with Ph2SNH (ratio 1:2) in MeCN via a metal assisted addition of the sulfimide to the acetonitrile to give [Pt(Ph2SNH)(Ph2SNC(Me)NH)CI]Cl . MeCN, the first example of a complex of the bidentate [Ph2SNC(Me)N(H)] ligand.

AB - In contrast to similar reactions of Cu, Co and Pd species, the platinum(II) complex [Pt(MeCN)(2)Cl-2] reacts with Ph2SNH (ratio 1:2) in MeCN via a metal assisted addition of the sulfimide to the acetonitrile to give [Pt(Ph2SNH)(Ph2SNC(Me)NH)CI]Cl . MeCN, the first example of a complex of the bidentate [Ph2SNC(Me)N(H)] ligand.

KW - COMPLEXES

KW - PALLADIUM

UR - http://www.scopus.com/inward/record.url?scp=0033591659&partnerID=8YFLogxK

M3 - Article

SN - 1359-7345

SP - 1081

EP - 1082

JO - Chemical Communications

JF - Chemical Communications

ER -

Formation of the bidentate [Ph₂SNC(Me)N(H)] ligand by metal-assisted sulfimide addition to acetonitrile; X-ray crystal structure of [Pt(Ph₂SNH)(Ph₂SNC(Me)NH)Cl]Cl.MeCN

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Keywords

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