Formation of a σ-alkane complex and a molecular rearrangement in the solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4]

Alasdair I. McKay; Tobias Krämer; Nicholas H. Rees; Amber L. Thompson; Kirsten E. Christensen; Stuart A. Macgregor; Andrew S. Weller

doi:10.1021/acs.organomet.6b00645

Formation of a σ-alkane complex and a molecular rearrangement in the solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4]

Alasdair I. McKay, Tobias Krämer, Nicholas H. Rees, Amber L. Thompson, Kirsten E. Christensen, Stuart A. Macgregor, Andrew S. Weller^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H12)][BArF 4] by a single-crystal to single-crystal reaction, as characterized by Xray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.

Original language	English
Pages (from-to)	22-25
Number of pages	4
Journal	Organometallics
Volume	36
Issue number	1
DOIs	https://doi.org/10.1021/acs.organomet.6b00645
Publication status	Published - 9 Jan 2017

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title = "Formation of a σ-alkane complex and a molecular rearrangement in the solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4]",

abstract = "Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H12)][BArF 4] by a single-crystal to single-crystal reaction, as characterized by Xray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.",

author = "McKay, {Alasdair I.} and Tobias Kr{\"a}mer and Rees, {Nicholas H.} and Thompson, {Amber L.} and Christensen, {Kirsten E.} and Macgregor, {Stuart A.} and Weller, {Andrew S.}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2017",

month = jan,

day = "9",

doi = "10.1021/acs.organomet.6b00645",

language = "English",

volume = "36",

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journal = "Organometallics",

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TY - JOUR

T1 - Formation of a σ-alkane complex and a molecular rearrangement in the solid-State

T2 - [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4]

AU - McKay, Alasdair I.

AU - Krämer, Tobias

AU - Rees, Nicholas H.

AU - Thompson, Amber L.

AU - Christensen, Kirsten E.

AU - Macgregor, Stuart A.

AU - Weller, Andrew S.

PY - 2017/1/9

Y1 - 2017/1/9

N2 - Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H12)][BArF 4] by a single-crystal to single-crystal reaction, as characterized by Xray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.

AB - Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H12)][BArF 4] by a single-crystal to single-crystal reaction, as characterized by Xray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.

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DO - 10.1021/acs.organomet.6b00645

M3 - Article

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SN - 0276-7333

VL - 36

SP - 22

EP - 25

JO - Organometallics

JF - Organometallics

IS - 1

ER -

Formation of a σ-alkane complex and a molecular rearrangement in the solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4]

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