Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

Byron Truscott; Fady Nahra; Alexandra Martha Zoya Slawin; David Bradford Cordes; Steven Patrick Nolan

doi:10.1039/c4cc07772e

Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

Byron Truscott, Fady Nahra, Alexandra Martha Zoya Slawin, David Bradford Cordes, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed.

Original language	English
Pages (from-to)	62-65
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	1
Early online date	27 Oct 2014
DOIs	https://doi.org/10.1039/c4cc07772e
Publication status	Published - 4 Jan 2015

Access to Document

10.1039/c4cc07772e

Nolan_2015_CC_Fluoride_AM
Copyright 2014 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/c4cc07772e
Accepted author manuscript, 754 KB

Cite this

@article{122c2bed892346258e96e03156168ebd,

title = "Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)",

abstract = "Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed.",

author = "Byron Truscott and Fady Nahra and Slawin, {Alexandra Martha Zoya} and Cordes, {David Bradford} and Nolan, {Steven Patrick}",

note = "The ERC (Advanced Researcher Award FUNCAT to SPN), the EPSRC and Sasol (Stipend to BJT) are gratefully acknowledged for support. ",

year = "2015",

month = jan,

day = "4",

doi = "10.1039/c4cc07772e",

language = "English",

volume = "51",

pages = "62--65",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

AU - Truscott, Byron

AU - Nahra, Fady

AU - Slawin, Alexandra Martha Zoya

AU - Cordes, David Bradford

AU - Nolan, Steven Patrick

N1 - The ERC (Advanced Researcher Award FUNCAT to SPN), the EPSRC and Sasol (Stipend to BJT) are gratefully acknowledged for support.

PY - 2015/1/4

Y1 - 2015/1/4

N2 - Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed.

AB - Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed.

UR - http://www.rsc.org/suppdata/cc/c4/c4cc07772e/c4cc07772e1.pdf

U2 - 10.1039/c4cc07772e

DO - 10.1039/c4cc07772e

M3 - Article

SN - 1359-7345

VL - 51

SP - 62

EP - 65

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

Abstract

Access to Document

Other files and links

Fingerprint

Structuring the Future: Structuring the Future - Underpinning world-leading science in EaStCHEM through cutting edge characterisation

Upgrade Small Equipment Base: Small items of research equipment at the University of St Andrews. Supporting a new generation of physical sciences research

FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis