Fluoren-9-one 4-toluenesulfonylhydrazone: hydrogen-bonded R22(8) dimers are linked into sheets by π...π stacking interactions

Christopher Glidewell; JN Low; JMS Skakle; JL Wardell

doi:10.1107/S1600536804004878

Fluoren-9-one 4-toluenesulfonylhydrazone: hydrogen-bonded R²₂(8) dimers are linked into sheets by π...π stacking interactions

Christopher Glidewell
, JN Low
, JMS Skakle
, JL Wardell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Molecules of the title compound, C20H16N2O2S, are linked into centrosymmetric R-2(2)(8) dimers by paired N-H...O hydrogen bonds [H...O 2.14 Angstrom, N...O 2.9951 (15) Angstrom and N-H...O 164degrees]. Two distinct pi-pi stacking interactions link the dimers into chains along [101] and [001], respectively, hence forming (010) sheets.

Original language	English
Pages (from-to)	o520-o522
Number of pages	3
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	E60
DOIs	https://doi.org/10.1107/S1600536804004878
Publication status	Published - Apr 2004

Keywords

POWDER DIFFRACTION DATA
CRYSTAL STRUCTURE
2,4,6-TRIISOPROPYLBENZENESULFONAMIDE

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title = "Fluoren-9-one 4-toluenesulfonylhydrazone: hydrogen-bonded R22(8) dimers are linked into sheets by π...π stacking interactions",

abstract = "Molecules of the title compound, C20H16N2O2S, are linked into centrosymmetric R-2(2)(8) dimers by paired N-H...O hydrogen bonds [H...O 2.14 Angstrom, N...O 2.9951 (15) Angstrom and N-H...O 164degrees]. Two distinct pi-pi stacking interactions link the dimers into chains along [101] and [001], respectively, hence forming (010) sheets.",

keywords = "POWDER DIFFRACTION DATA, CRYSTAL STRUCTURE, 2,4,6-TRIISOPROPYLBENZENESULFONAMIDE",

author = "Christopher Glidewell and JN Low and JMS Skakle and JL Wardell",

year = "2004",

month = apr,

doi = "10.1107/S1600536804004878",

language = "English",

volume = "E60",

pages = "o520--o522",

journal = "Acta Crystallographica. Section E, Structure reports online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Fluoren-9-one 4-toluenesulfonylhydrazone: hydrogen-bonded R22(8) dimers are linked into sheets by π...π stacking interactions

AU - Glidewell, Christopher

AU - Low, JN

AU - Skakle, JMS

AU - Wardell, JL

PY - 2004/4

Y1 - 2004/4

N2 - Molecules of the title compound, C20H16N2O2S, are linked into centrosymmetric R-2(2)(8) dimers by paired N-H...O hydrogen bonds [H...O 2.14 Angstrom, N...O 2.9951 (15) Angstrom and N-H...O 164degrees]. Two distinct pi-pi stacking interactions link the dimers into chains along [101] and [001], respectively, hence forming (010) sheets.

AB - Molecules of the title compound, C20H16N2O2S, are linked into centrosymmetric R-2(2)(8) dimers by paired N-H...O hydrogen bonds [H...O 2.14 Angstrom, N...O 2.9951 (15) Angstrom and N-H...O 164degrees]. Two distinct pi-pi stacking interactions link the dimers into chains along [101] and [001], respectively, hence forming (010) sheets.

KW - POWDER DIFFRACTION DATA

KW - CRYSTAL STRUCTURE

KW - 2,4,6-TRIISOPROPYLBENZENESULFONAMIDE

U2 - 10.1107/S1600536804004878

DO - 10.1107/S1600536804004878

M3 - Article

SN - 1600-5368

VL - E60

SP - o520-o522

JO - Acta Crystallographica. Section E, Structure reports online

JF - Acta Crystallographica. Section E, Structure reports online

ER -