Flexible cycloalkyl-substituted N-heterocyclic carbenes

George C. Fortman; Alexandra M. Z. Slawin; Steven Patrick Nolan

doi:10.1039/c003214j

Flexible cycloalkyl-substituted N-heterocyclic carbenes

George C. Fortman
, Alexandra M. Z. Slawin
, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The use of two metal systems cis-Pt(NHC)(2)Me-2 and cis-Ir(NHC)(CO)(2)Cl help to highlight the. exibility of a series of cycloalkyl-substituted N-heterocyclic carbene ligands (ICy, ICy7, ICy8, ICy12). Bond dissociation enthalpies of several N-heterocyclic carbenes (NHCs) in cis-Pt(NHC)(2)Me-2 are estimated. Electronic and steric parameters of the ICyn ligands are quantified and discussed.

Original language	English
Pages (from-to)	3923-3930
Number of pages	8
Journal	Dalton Transactions
Volume	39
Issue number	16
DOIs	https://doi.org/10.1039/c003214j
Publication status	Published - 2010

Keywords

RESTRICTED FLEXIBILITY
COMPLEXES
LIGANDS
CATALYSIS
IRIDIUM
METAL
RHODIUM
SYSTEM

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title = "Flexible cycloalkyl-substituted N-heterocyclic carbenes",

abstract = "The use of two metal systems cis-Pt(NHC)(2)Me-2 and cis-Ir(NHC)(CO)(2)Cl help to highlight the. exibility of a series of cycloalkyl-substituted N-heterocyclic carbene ligands (ICy, ICy7, ICy8, ICy12). Bond dissociation enthalpies of several N-heterocyclic carbenes (NHCs) in cis-Pt(NHC)(2)Me-2 are estimated. Electronic and steric parameters of the ICyn ligands are quantified and discussed.",

keywords = "RESTRICTED FLEXIBILITY, COMPLEXES, LIGANDS, CATALYSIS, IRIDIUM, METAL, RHODIUM, SYSTEM",

author = "Fortman, \{George C.\} and Slawin, \{Alexandra M. Z.\} and Nolan, \{Steven Patrick\}",

year = "2010",

doi = "10.1039/c003214j",

language = "English",

volume = "39",

pages = "3923--3930",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - Flexible cycloalkyl-substituted N-heterocyclic carbenes

AU - Fortman, George C.

AU - Slawin, Alexandra M. Z.

AU - Nolan, Steven Patrick

PY - 2010

Y1 - 2010

N2 - The use of two metal systems cis-Pt(NHC)(2)Me-2 and cis-Ir(NHC)(CO)(2)Cl help to highlight the. exibility of a series of cycloalkyl-substituted N-heterocyclic carbene ligands (ICy, ICy7, ICy8, ICy12). Bond dissociation enthalpies of several N-heterocyclic carbenes (NHCs) in cis-Pt(NHC)(2)Me-2 are estimated. Electronic and steric parameters of the ICyn ligands are quantified and discussed.

AB - The use of two metal systems cis-Pt(NHC)(2)Me-2 and cis-Ir(NHC)(CO)(2)Cl help to highlight the. exibility of a series of cycloalkyl-substituted N-heterocyclic carbene ligands (ICy, ICy7, ICy8, ICy12). Bond dissociation enthalpies of several N-heterocyclic carbenes (NHCs) in cis-Pt(NHC)(2)Me-2 are estimated. Electronic and steric parameters of the ICyn ligands are quantified and discussed.

KW - RESTRICTED FLEXIBILITY

KW - COMPLEXES

KW - LIGANDS

KW - CATALYSIS

KW - IRIDIUM

KW - METAL

KW - RHODIUM

KW - SYSTEM

UR - https://www.scopus.com/pages/publications/77950473214

U2 - 10.1039/c003214j

DO - 10.1039/c003214j

M3 - Article

SN - 1477-9226

VL - 39

SP - 3923

EP - 3930

JO - Dalton Transactions

JF - Dalton Transactions

IS - 16

ER -

Flexible cycloalkyl-substituted N-heterocyclic carbenes

Abstract

Keywords

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