Flash Vacuum Pyrolysis of Sulphonyl Stabilised Phosphorus Ylides: Generation and Reactivity of Sulphonyl Carbenes

R Alan Aitken; M J  DRYSDALE

Flash Vacuum Pyrolysis of Sulphonyl Stabilised Phosphorus Ylides: Generation and Reactivity of Sulphonyl Carbenes

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Abstract

Thermal decomposition of arylmethylsulphonylalkylidenetriphenylphosphoranes results in loss of Ph3P and SO2 to give alkenes and in some cases products derived from benzylic radicals, the products are explained by a mechanism involving sulphonyl carbenes.

Original language	English
Pages (from-to)	512-513
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	7
Publication status	Published - 1 Apr 1991

Cite this

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title = "Flash Vacuum Pyrolysis of Sulphonyl Stabilised Phosphorus Ylides: Generation and Reactivity of Sulphonyl Carbenes",

abstract = "Thermal decomposition of arylmethylsulphonylalkylidenetriphenylphosphoranes results in loss of Ph3P and SO2 to give alkenes and in some cases products derived from benzylic radicals, the products are explained by a mechanism involving sulphonyl carbenes.",

author = "Aitken, {R Alan} and DRYSDALE, {M J}",

year = "1991",

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T1 - Flash Vacuum Pyrolysis of Sulphonyl Stabilised Phosphorus Ylides

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AU - DRYSDALE, M J

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AB - Thermal decomposition of arylmethylsulphonylalkylidenetriphenylphosphoranes results in loss of Ph3P and SO2 to give alkenes and in some cases products derived from benzylic radicals, the products are explained by a mechanism involving sulphonyl carbenes.

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M3 - Article

SN - 0022-4936

SP - 512

EP - 513

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 7

ER -

Flash Vacuum Pyrolysis of Sulphonyl Stabilised Phosphorus Ylides: Generation and Reactivity of Sulphonyl Carbenes

Abstract

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