Flash Vacuum Pyrolysis of Sulfinyl Stabilised Phosphorus Ylides: Generation and Reactivity of Sulfinylcarbenes

R Alan Aitken; M J  DRYSDALE; B M  RYAN

Flash Vacuum Pyrolysis of Sulfinyl Stabilised Phosphorus Ylides: Generation and Reactivity of Sulfinylcarbenes

R Alan Aitken, M J DRYSDALE, B M RYAN

Research output: Contribution to journal › Article › peer-review

Abstract

Flash vacuum pyrolysis of alpha-alkanesulfinyl phosphorus ylides results mainly in extrusion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for alpha-arenesulfinyl ylides loss of Ph3PO to give additional products is also observed.

Original language	English
Pages (from-to)	1699-1700
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
Publication status	Published - 21 Nov 1993

Keywords

ELEMENTO-ORGANIC COMPOUNDS
6TH GROUPS
ACETYLENES
ACYL
5TH

Cite this

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title = "Flash Vacuum Pyrolysis of Sulfinyl Stabilised Phosphorus Ylides: Generation and Reactivity of Sulfinylcarbenes",

abstract = "Flash vacuum pyrolysis of alpha-alkanesulfinyl phosphorus ylides results mainly in extrusion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for alpha-arenesulfinyl ylides loss of Ph3PO to give additional products is also observed.",

keywords = "ELEMENTO-ORGANIC COMPOUNDS, 6TH GROUPS, ACETYLENES, ACYL, 5TH",

author = "Aitken, \{R Alan\} and DRYSDALE, \{M J\} and RYAN, \{B M\}",

year = "1993",

month = nov,

day = "21",

language = "English",

pages = "1699--1700",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "22",

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T1 - Flash Vacuum Pyrolysis of Sulfinyl Stabilised Phosphorus Ylides

T2 - Generation and Reactivity of Sulfinylcarbenes

AU - Aitken, R Alan

AU - DRYSDALE, M J

AU - RYAN, B M

PY - 1993/11/21

Y1 - 1993/11/21

N2 - Flash vacuum pyrolysis of alpha-alkanesulfinyl phosphorus ylides results mainly in extrusion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for alpha-arenesulfinyl ylides loss of Ph3PO to give additional products is also observed.

AB - Flash vacuum pyrolysis of alpha-alkanesulfinyl phosphorus ylides results mainly in extrusion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for alpha-arenesulfinyl ylides loss of Ph3PO to give additional products is also observed.

KW - ELEMENTO-ORGANIC COMPOUNDS

KW - 6TH GROUPS

KW - ACETYLENES

KW - ACYL

KW - 5TH

UR - https://www.scopus.com/pages/publications/37049075478

M3 - Article

SN - 0022-4936

SP - 1699

EP - 1700

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 22

ER -

Flash Vacuum Pyrolysis of Sulfinyl Stabilised Phosphorus Ylides: Generation and Reactivity of Sulfinylcarbenes

Abstract

Keywords

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